A. S. Chistyakov, M. A. Shmelev, L. M. Efromeev, L. D. Popov, Yu. K. Voronina, A. A. Sidorov, I. L. Eremenko
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引用次数: 0
Abstract
A series of copper(II), nickel(II), and cadmium(II) compounds with pivalate (Piv) or pentafluorobenzoate (Pfb) anions and 2-amino-1-methylbenzimidazole (L) molecules, [Cu2(Piv)4(L)2]·2MeCN (I), [Ni(Piv)2(L)2][Ni(Piv)2(L)2(MeOH)] (II), and [Cd(Pfb)2(L)2] (III), were obtained. In the case of copper compounds, a binuclear complex with a Chinese lantern structure was formed, while nickel and cadmium salts resulted in the formation of mononuclear complexes. In all synthesized compounds, the 2-amino-1-methylbenzimidazole molecule is a monodentate ligand, coordinated to the metal atom via the nitrogen atom of the benzimidazole ring. The compounds were characterized by X-ray diffraction, IR spectroscopy, and CHN analysis.
期刊介绍：
Russian Journal of Coordination Chemistry is a journal that publishes reviews, original papers, and short communications on all aspects of theoretical and experimental coordination chemistry. Modern coordination chemistry is an interdisciplinary science that makes a bridge between inorganic, organic, physical, analytical, and biological chemistry.
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