One-Step Process for Ultrasensitive Detection of Mercuric Ions using Nanoparticle Formation and Single-Entity Electrochemistry

Abstract

Mercuric ions (Hg²⁺) are common heavy-metal ions that pose a significant threat to human health due to their high toxicity. The detection of excessive concentrations of Hg²⁺ is critical and requires highly sensitive electrochemical techniques. A novel electrochemical sensing technique was employed for the detection of Hg²⁺. This study emphasizes the use of single-entity electrochemistry (SEE) for the one-step synthesis and selective detection of nanoparticles in aqueous solutions. Importantly, this method does not require a catalyst or reducing agent for nanoparticle synthesis. The developed approach provides significant advantages over conventional techniques, such as increased sensitivity, improved selectivity, and the ability to detect low concentrations of 1 pM Hg²⁺ without modifying the electrode surface and the linear range for Hg²⁺ was obtained at 1 pM – 10 nM. This one-step synthesis and detection method is a reliable and promising tool for sensing trace heavy metals and studying the redox behavior of mercuric ions.