Synthesis and characterisation of biodegradable polyurethane/CuS nanocomposites for agricultural application

IF 3.1 3区 化学 Q2 POLYMER SCIENCE
S. Poornima, V. L. Yashaswini, S. Roopa, B. S. Madhukar, M. A. Sangamesha
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引用次数: 0

Abstract

Polyurethane (PU) is one of the important industrial polymers. PU and its composites can be used in different applications. This paper examines the potential of PU/copper sulphide (CuS) nanocomposites (NCs) for application as green mulching films in agriculture. Castor oil-based PU NCs were fabricated by varying the CuS concentration viz., 0.0%, 1.0%, 2.0%, 4.0% and 8.0%. The NCs were characterised for microcrystalline nature by X-ray diffraction, Fourier transform infrared spectroscopy used for examining spectral characteristics, morphological assessment by scanning electron microscopy and elemental analysis by energy-dispersive x-ray Spectroscopy. The NCs were characterised for tensile properties, which revealed that a 4% PU/CuS nanocomposite (NC) exhibited high elongation at break of 399.72 MPa, suitable for mulching applications. Thermogravimetric analysis was used to examine the thermal stability and degradation. The chemical resistance and water absorption were evaluated in various atmosphere. The biodegradability was investigated through the soil and cow dung burial test. The pot study experiment is conducted to investigate the effect of NC on growth rate of the plants, which showed that beans treated with PU/CuS NC showed a 43% increase in height within 7 days and a 32% increase within 35 days, with an increase of about 62.5% in leaf width within 7 days and continues to increase until the 35th day and shows considerably more branches and stem diameter than the control. This work concludes that PU/CuS NCs have high potential as green mulching films for application in agriculture.

Graphical abstract

农业用可生物降解聚氨酯/ cu纳米复合材料的合成与表征
聚氨酯(PU)是重要的工业聚合物之一。PU及其复合材料可用于不同的用途。研究了聚氨酯/硫化铜纳米复合材料作为农业绿色地膜的应用前景。分别以0.0%、1.0%、2.0%、4.0%和8.0%的CuS浓度制备蓖麻油基PU nc。通过x射线衍射、傅里叶变换红外光谱、扫描电子显微镜和能量色散x射线光谱分析对nc进行了微晶性质表征。对纳米复合材料的拉伸性能进行了表征,结果表明,4% PU/ cu纳米复合材料(NC)的断裂伸长率高达399.72 MPa,适合覆盖应用。用热重分析法考察了其热稳定性和降解性。在不同气氛下对其耐化学性和吸水性进行了评价。通过土壤和牛粪掩埋试验考察了其生物降解性。盆栽试验研究了NC对植株生长速率的影响,结果表明,PU/ cu NC处理的豆类在7 d内长高43%,35 d内长高32%,叶片宽度在7 d内增长约62.5%,并持续增长至35 d,分枝和茎粗明显大于对照。研究结果表明,PU/ cu NCs作为绿色地膜在农业上具有很大的应用潜力。图形抽象
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来源期刊
Polymer Bulletin
Polymer Bulletin 化学-高分子科学
CiteScore
6.00
自引率
6.20%
发文量
0
审稿时长
5.5 months
期刊介绍: "Polymer Bulletin" is a comprehensive academic journal on polymer science founded in 1988. It was founded under the initiative of the late Mr. Wang Baoren, a famous Chinese chemist and educator. This journal is co-sponsored by the Chinese Chemical Society, the Institute of Chemistry, and the Chinese Academy of Sciences and is supervised by the China Association for Science and Technology. It is a core journal and is publicly distributed at home and abroad. "Polymer Bulletin" is a monthly magazine with multiple columns, including a project application guide, outlook, review, research papers, highlight reviews, polymer education and teaching, information sharing, interviews, polymer science popularization, etc. The journal is included in the CSCD Chinese Science Citation Database. It serves as the source journal for Chinese scientific and technological paper statistics and the source journal of Peking University's "Overview of Chinese Core Journals."
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