Dan Qin, Tao Liu, Xiang Wang, Xuehui Zhang, Wenmin Zhao, Longfei Zeng
{"title":"Study on microstructure and properties of Cu-SnO2 composites prepared by in-situ supercritical water reaction method","authors":"Dan Qin, Tao Liu, Xiang Wang, Xuehui Zhang, Wenmin Zhao, Longfei Zeng","doi":"10.1016/j.ceramint.2024.12.013","DOIUrl":null,"url":null,"abstract":"<div><div>In this study, Cu-SnO<sub>2</sub> composites are successfully prepared using supercritical water in-situ oxidation and powder metallurgy techniques. The results demonstrate that the Cu-4.5 wt% SnO<sub>2</sub> composite possessed excellent comprehensive performance. The tensile strength of the composite is 331 MPa, represents a 36.21 % increase compared to pure copper. The elongation is 43.21 %, and the hardness after treatment at 1000 °C is 87.26 HV, which is 85.76 % of the untreated hardness. These properties are attributed to the specific orientation relationship of SnO<sub>2</sub> with the Cu matrix {[<span><math><mrow><mn>1</mn><mover><mn>1</mn><mo>‾</mo></mover><mover><mn>1</mn><mo>‾</mo></mover></mrow></math></span>]<sub>SnO2</sub>//[<span><math><mrow><mover><mn>1</mn><mo>‾</mo></mover><mn>00</mn></mrow></math></span>]<sub>Cu</sub>, (<span><math><mrow><mn>12</mn><mover><mn>1</mn><mo>‾</mo></mover></mrow></math></span>)<sub>SnO2</sub>//(<span><math><mrow><mn>020</mn></mrow></math></span>)<sub>Cu</sub>}, with SnO<sub>2</sub> particles homogeneously dispersed in the composite.</div></div>","PeriodicalId":267,"journal":{"name":"Ceramics International","volume":"51 5","pages":"Pages 5659-5669"},"PeriodicalIF":5.1000,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Ceramics International","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0272884224056463","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, CERAMICS","Score":null,"Total":0}
引用次数: 0
Abstract
In this study, Cu-SnO2 composites are successfully prepared using supercritical water in-situ oxidation and powder metallurgy techniques. The results demonstrate that the Cu-4.5 wt% SnO2 composite possessed excellent comprehensive performance. The tensile strength of the composite is 331 MPa, represents a 36.21 % increase compared to pure copper. The elongation is 43.21 %, and the hardness after treatment at 1000 °C is 87.26 HV, which is 85.76 % of the untreated hardness. These properties are attributed to the specific orientation relationship of SnO2 with the Cu matrix {[]SnO2//[]Cu, ()SnO2//()Cu}, with SnO2 particles homogeneously dispersed in the composite.
期刊介绍:
Ceramics International covers the science of advanced ceramic materials. The journal encourages contributions that demonstrate how an understanding of the basic chemical and physical phenomena may direct materials design and stimulate ideas for new or improved processing techniques, in order to obtain materials with desired structural features and properties.
Ceramics International covers oxide and non-oxide ceramics, functional glasses, glass ceramics, amorphous inorganic non-metallic materials (and their combinations with metal and organic materials), in the form of particulates, dense or porous bodies, thin/thick films and laminated, graded and composite structures. Process related topics such as ceramic-ceramic joints or joining ceramics with dissimilar materials, as well as surface finishing and conditioning are also covered. Besides traditional processing techniques, manufacturing routes of interest include innovative procedures benefiting from externally applied stresses, electromagnetic fields and energetic beams, as well as top-down and self-assembly nanotechnology approaches. In addition, the journal welcomes submissions on bio-inspired and bio-enabled materials designs, experimentally validated multi scale modelling and simulation for materials design, and the use of the most advanced chemical and physical characterization techniques of structure, properties and behaviour.
Technologically relevant low-dimensional systems are a particular focus of Ceramics International. These include 0, 1 and 2-D nanomaterials (also covering CNTs, graphene and related materials, and diamond-like carbons), their nanocomposites, as well as nano-hybrids and hierarchical multifunctional nanostructures that might integrate molecular, biological and electronic components.