Room-temperature near-infrared phosphorescence of a bismuthinidene N,C,N pincer complex†

IF 4.2 2区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY
Katharina L. Deuter, Daisy J. J. Balaba, Michael Linseis and Rainer F. Winter
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引用次数: 0

Abstract

We report on the emissive properties of two related bismuth complexes, LBiBr2 and LBi, with a monoanionic 2,6-diiminophenyl N,C,N pincer ligand L. The Bi(III) complex phosphoresces at 77 K, while the bismuthinidene Bi(I) species represents the first example of a phosphorescent bismuth complex that emits in the near infrared at room temperature.

Abstract Image

氮、碳、氮螯合物的室温近红外磷光。
我们报道了两种相关的铋配合物LBiBr2和LBi的发射特性,它们与单阴离子2,6-二亚苯基N,C,N螯合体l相结合。Bi(III)配合物在77 K时发光,而铋铋Bi(I)是在室温下发射近红外的磷光铋配合物的第一个例子。
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来源期刊
Chemical Communications
Chemical Communications 化学-化学综合
CiteScore
8.60
自引率
4.10%
发文量
2705
审稿时长
1.4 months
期刊介绍: ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.
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