{"title":"Spin-Coating Se in Precursor to Improve Absorber Crystallinity and Reduce Defects Enabling 13.57% Efficiency for Kesterite Solar Cells","authors":"Yuanyuan Wang, Jiaqi Wang, Zucheng Wu, Yuena Meng, Jichun Zhu, Dongxing Kou, Wenhui Zhou, Zhengji Zhou, Yafang Qi, Shengjie Yuan, Litao Han, Sixin Wu","doi":"10.1002/solr.202400735","DOIUrl":null,"url":null,"abstract":"<p>Poor crystallinity is a common problem of kesterite absorbers based on non-hydrazine solution method, which obstructs charge transfer and affects photovoltaic performance of the thin-film devices, especially the open-circuit voltage (<i>V</i><sub>OC</sub>). Se diffusion is often insufficient during the crystal growth of kesterite absorber, resulting in uneven selenization reaction. Herein, Se molecule is introduced into kesterite precursor film to promote the absorber crystallinity while preventing the formation of a thick Mo(Se,S)<sub>2</sub> layer. It is found that after Se-introduction treatment, Se element distributes more uniformly in the absorber film after high-temperature annealing. During selenization, the lower part of the precursor film can easily obtain Se and experience crystallization, thus promoting the crystallization of the whole absorber. As a result, the absorber defects are passivated. According to charge carrier characterization, the carrier lifetime of the device is prolonged due to the reduced carrier recombination centers. Finally, a champion device with the <i>V</i><sub>OC</sub> increases by 23 mV, and an efficiency of 12.39% (active area efficiency of 13.57%) is achieved.</p>","PeriodicalId":230,"journal":{"name":"Solar RRL","volume":"9 3","pages":""},"PeriodicalIF":6.0000,"publicationDate":"2025-01-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Solar RRL","FirstCategoryId":"5","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/solr.202400735","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENERGY & FUELS","Score":null,"Total":0}
引用次数: 0
Abstract
Poor crystallinity is a common problem of kesterite absorbers based on non-hydrazine solution method, which obstructs charge transfer and affects photovoltaic performance of the thin-film devices, especially the open-circuit voltage (VOC). Se diffusion is often insufficient during the crystal growth of kesterite absorber, resulting in uneven selenization reaction. Herein, Se molecule is introduced into kesterite precursor film to promote the absorber crystallinity while preventing the formation of a thick Mo(Se,S)2 layer. It is found that after Se-introduction treatment, Se element distributes more uniformly in the absorber film after high-temperature annealing. During selenization, the lower part of the precursor film can easily obtain Se and experience crystallization, thus promoting the crystallization of the whole absorber. As a result, the absorber defects are passivated. According to charge carrier characterization, the carrier lifetime of the device is prolonged due to the reduced carrier recombination centers. Finally, a champion device with the VOC increases by 23 mV, and an efficiency of 12.39% (active area efficiency of 13.57%) is achieved.
Solar RRLPhysics and Astronomy-Atomic and Molecular Physics, and Optics
CiteScore
12.10
自引率
6.30%
发文量
460
期刊介绍:
Solar RRL, formerly known as Rapid Research Letters, has evolved to embrace a broader and more encompassing format. We publish Research Articles and Reviews covering all facets of solar energy conversion. This includes, but is not limited to, photovoltaics and solar cells (both established and emerging systems), as well as the development, characterization, and optimization of materials and devices. Additionally, we cover topics such as photovoltaic modules and systems, their installation and deployment, photocatalysis, solar fuels, photothermal and photoelectrochemical solar energy conversion, energy distribution, grid issues, and other relevant aspects. Join us in exploring the latest advancements in solar energy conversion research.