Intricacies of Carbon Dot Photoluminescence for Emerging Applications: A Review.

Abstract

Discovered in 2004, carbon dots (CDs) have already traversed a long journey, generating many promising research directions. Its cheapness, ease of synthesis, high water-solubility, tunable emission, and excellent biocompatibility make it a single-point solution to many problems, and tremendous efforts were invested into understanding the structure-property-function relationship, which eases the engineering of the CD properties suitable for a desired application. From the usual random choice of precursors or carbon materials as a starting point in the early days, more systematic approaches are now available for choosing proper starting materials and appropriate experimental conditions (solvent medium, reaction temperature, reaction duration, pH, etc) to customize its photoluminescence. The presence of impurities has a crucial role in the outcome and applicability of photoluminescence. Recently, a significant focus has been on the long-wavelength emissive CDs, particularly in the red to near-infrared (NIR) regions, for better penetration into live cells and to circumvent autofluorescence problems. Proper design can harvest phosphorescence from CDs. Many excellent reviews are available, focusing on different facets of CD prospects. Hence, we will only highlight the importance of the optical properties of CDs. We will mention some of the new works that have appeared in the last five years.