Borole Ring Expansion Reactions with Boron Azides: A Versatile Pathway to Borylated Azaborinines

IF 2.2 4区化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR

European Journal of Inorganic Chemistry Pub Date : 2024-11-13 DOI:10.1002/ejic.202400498

Dr. Felix Lindl, Dr. Torsten Thiess, Dr. James T. Goettel, Dr. Simon Dotzauer, Dr. Moritz Johannes Ernst, Prof. Dr. Guillaume Bélanger-Chabot, Prof. Dr. Holger Braunschweig

引用次数: 0

Abstract

The reaction of boroles with organic azides is known to straightforwardly yield 1,2-azaborinines, which have generated significant interest as benzene bioisosteres. We show that this powerful synthetic pattern extends to a variety of structurally and chemically diverse boron azides, including recently reported diborane(4) azides. This provides a general, powerful borylation method to expand the chemistry of 1,2-azaborinines.

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众所周知，硼化物与有机叠氮化物反应可直接生成 1,2-氮杂硼烷，这引起了人们对苯生物异养生物的极大兴趣。我们的研究表明，这种强大的合成模式可以扩展到各种结构和化学性质不同的硼叠氮化物，包括最近报道的二硼烷（4）叠氮化物。这为拓展 1,2-氮杂硼烷的化学性质提供了一种通用、强大的硼酰化方法。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

European Journal of Inorganic Chemistry 化学-无机化学与核化学

CiteScore

4.30

自引率

4.30%

发文量

419

审稿时长

1.3 months

期刊介绍： The European Journal of Inorganic Chemistry (2019 ISI Impact Factor: 2.529) publishes Full Papers, Communications, and Minireviews from the entire spectrum of inorganic, organometallic, bioinorganic, and solid-state chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies. The following journals have been merged to form the two leading journals, European Journal of Inorganic Chemistry and European Journal of Organic Chemistry: Chemische Berichte Bulletin des Sociétés Chimiques Belges Bulletin de la Société Chimique de France Gazzetta Chimica Italiana Recueil des Travaux Chimiques des Pays-Bas Anales de Química Chimika Chronika Revista Portuguesa de Química ACH—Models in Chemistry Polish Journal of Chemistry The European Journal of Inorganic Chemistry continues to keep you up-to-date with important inorganic chemistry research results.