Optical and photoluminescence characteristics of Pr3+-doped P2O5 +BaO+La2O3 glasses

IF 3.8 Q2 CHEMISTRY, PHYSICAL

Chemical Physics Impact Pub Date : 2024-12-07 DOI:10.1016/j.chphi.2024.100797

C.R. Kesavulu , Ch. Basavapoornima , Pikkili Ramprasad , C.J. Deviprasad , Shobha Rani Depuru , C.K. Jayasankar

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Abstract

This paper focusses on the spectral analysis of glasses composed of Pr³⁺:barium phosphate (PBaLaPr), which are employed in visible lasers and optical amplifiers. FTIR analysis of the vibrational modes of Pr³⁺:barium phosphate glasses has been studied. Using the absorption spectra, the three Judd-Ofelt (JO) parameters (Ω_2,4,6) were calculated. The resultant JO values (× 10^–20 cm²) were estimated to be Ω₂ = 3.49, Ω₄ = 22.06, and Ω₆ = 20.48. The radiative probabilities for the fluorescence states of Pr³⁺ were determined. The luminescence spectra show the emission bands in the visible range of 480–750 nm, and when the concentration of Pr³⁺ ions increased, decrease in emission intensities is observed due to concentration quenching. A luminescence peak at 600 nm was used as a monitoring level, and a 445 nm excitation was used to assess the decay curves. The decay rates exhibit a bi-exponential pattern, meaning that as the concentration of Pr³⁺ ions increase, the lifetimes become shorter. The near infrared luminescence characteristics were studied (λ_exe = 488 nm), and the resultant spectrum contains three emission bands, ranging from 800 to 1600 nm. The results of the investigation showed that the titled PBaLaPr glasses have potentiality for the development of VIS-NIR optical amplifiers and optical display devices.

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