Characterization of temperature-dependent full-matrix constants of [001]c-poled Mn-doped 28PIN-43PMN-29PT single crystals using one sample

IF 5.1 2区材料科学 Q1 MATERIALS SCIENCE, CERAMICS

Ceramics International Pub Date : 2025-01-01 DOI:10.1016/j.ceramint.2024.11.076

Kai Zhang , Ailing Xiao , Liguo Tang , Guisheng Xu , Wenyu Luo

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引用次数: 0

Abstract

[001]_c-poled Mn-doped xPb(In_1/2Nb_1/2)O₃–(1–x–y)Pb(Mg_1/3Nb_2/3)O₃–yPbTiO₃ (PIN–PMN–PT:Mn) single crystals (SCs) in the rhombohedral phase possess not only excellent piezoelectric properties but also a high mechanical quality factor, which make them suitable for fabricating high-performance piezoelectric devices. Characterizing the temperature dependence (TD) of full-matrix constants is indispensable for their use in device design. However, there is a significant lack of relevant data. In this study, the TD of the clamped dielectric properties of [001]_c-poled 28PIN-43PMN-29PT:Mn SCs was characterized using a dielectric temperature spectroscopy measurement system from 0 to 60 °C. Their elastic and piezoelectric constants were measured using resonant ultrasound spectroscopy in the same temperature range. With an increase in the temperature, all the elastic stiffness constants decreased, whereas all the clamped dielectric constants and the absolute values of all the piezoelectric stress constants increased. The characterization process required only a single sample, which ensured the consistency of the results. Furthermore, the electrical impedance spectra of the sample at 30 and 50 °C were measured and compared with those simulated using the finite-element method with the characterization results. The close agreement between them confirmed the reliability of the characterization results.

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来源期刊

Ceramics International 工程技术-材料科学：硅酸盐

CiteScore

9.40

自引率

15.40%

发文量

4558

审稿时长

25 days

期刊介绍： Ceramics International covers the science of advanced ceramic materials. The journal encourages contributions that demonstrate how an understanding of the basic chemical and physical phenomena may direct materials design and stimulate ideas for new or improved processing techniques, in order to obtain materials with desired structural features and properties. Ceramics International covers oxide and non-oxide ceramics, functional glasses, glass ceramics, amorphous inorganic non-metallic materials (and their combinations with metal and organic materials), in the form of particulates, dense or porous bodies, thin/thick films and laminated, graded and composite structures. Process related topics such as ceramic-ceramic joints or joining ceramics with dissimilar materials, as well as surface finishing and conditioning are also covered. Besides traditional processing techniques, manufacturing routes of interest include innovative procedures benefiting from externally applied stresses, electromagnetic fields and energetic beams, as well as top-down and self-assembly nanotechnology approaches. In addition, the journal welcomes submissions on bio-inspired and bio-enabled materials designs, experimentally validated multi scale modelling and simulation for materials design, and the use of the most advanced chemical and physical characterization techniques of structure, properties and behaviour. Technologically relevant low-dimensional systems are a particular focus of Ceramics International. These include 0, 1 and 2-D nanomaterials (also covering CNTs, graphene and related materials, and diamond-like carbons), their nanocomposites, as well as nano-hybrids and hierarchical multifunctional nanostructures that might integrate molecular, biological and electronic components.