Microwave plasma treatments for solvothermally grown NiCo-metalorganic frameworks on flexible carbon paper substrate

IF 5.5 3区工程技术 Q1 ENGINEERING, CHEMICAL

Journal of the Taiwan Institute of Chemical Engineers Pub Date : 2025-01-16 DOI:10.1016/j.jtice.2025.105973

Shuo-En Yu , Hsing-Chen Wu , I-Chun Cheng , Jian-Zhang Chen

{"title":"Microwave plasma treatments for solvothermally grown NiCo-metalorganic frameworks on flexible carbon paper substrate","authors":"Shuo-En Yu , Hsing-Chen Wu , I-Chun Cheng , Jian-Zhang Chen","doi":"10.1016/j.jtice.2025.105973","DOIUrl":null,"url":null,"abstract":"<div><h3>Background</h3><div>Devices fabricated on flexible substrates find diverse applications. The advancement of materials and manufacturing methods is critical for improving flexible devices.</div></div><div><h3>Method</h3><div>This study compares ultrafast Ar and O<sub>2</sub> microwave plasma (MP) treatments in terms of their high energy efficiency and high ionization rate to process solvothermally grown NiCo-metalorganic frameworks (NiCo-MOFs) on flexible carbon paper (CP) substrates.</div></div><div><h3>Significant Findings</h3><div>Ar MP treatment reduces the oxidation states to reveal metallic states, whereas O<sub>2</sub> MP treatment enhances the oxidation effect with no apparent metallic reduction. Samples treated with Ar MP become less hydrophilic whereas those treated with O<sub>2</sub> MP retain the hydrophilicity of pristine NiCo-MOFs. The oxidation capability of O<sub>2</sub> MP and reduction capability of Ar MP treatments can be beneficial for general materials processing.</div></div>","PeriodicalId":381,"journal":{"name":"Journal of the Taiwan Institute of Chemical Engineers","volume":"169 ","pages":"Article 105973"},"PeriodicalIF":5.5000,"publicationDate":"2025-01-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of the Taiwan Institute of Chemical Engineers","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1876107025000240","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}

引用次数: 0

Abstract

Background

Devices fabricated on flexible substrates find diverse applications. The advancement of materials and manufacturing methods is critical for improving flexible devices.

Method

This study compares ultrafast Ar and O₂ microwave plasma (MP) treatments in terms of their high energy efficiency and high ionization rate to process solvothermally grown NiCo-metalorganic frameworks (NiCo-MOFs) on flexible carbon paper (CP) substrates.

Significant Findings

Ar MP treatment reduces the oxidation states to reveal metallic states, whereas O₂ MP treatment enhances the oxidation effect with no apparent metallic reduction. Samples treated with Ar MP become less hydrophilic whereas those treated with O₂ MP retain the hydrophilicity of pristine NiCo-MOFs. The oxidation capability of O₂ MP and reduction capability of Ar MP treatments can be beneficial for general materials processing.

Abstract Image

查看原文本刊更多论文

求助全文

约1分钟内获得全文求助全文

来源期刊

Journal of the Taiwan Institute of Chemical Engineers 工程技术-工程：化工

CiteScore

9.10

自引率

14.00%

发文量

362

审稿时长

35 days

期刊介绍： Journal of the Taiwan Institute of Chemical Engineers (formerly known as Journal of the Chinese Institute of Chemical Engineers) publishes original works, from fundamental principles to practical applications, in the broad field of chemical engineering with special focus on three aspects: Chemical and Biomolecular Science and Technology, Energy and Environmental Science and Technology, and Materials Science and Technology. Authors should choose for their manuscript an appropriate aspect section and a few related classifications when submitting to the journal online.