Characterization and modification mechanism of recycled silty clay slurry as a shield slag conditioner: Macroscopic, mesoscopic, and microscopic multiscale analysis

Abstract

The large amount of slag generated during the construction of earth pressure balance shield (EPBS) not only incurs significant disposal costs, but also exacerbates environmental pollution. To improve the utilization of the shield slag, silty clay with additive is proposed as a slag conditioner instead of bentonite. Firstly, various macroscopic properties of the bentonite and silty clay slurries are tested. Subsequently, the relationships between the macroscopic properties of the silty clay slurries containing additives and the modification mechanism are evaluated at microscopic, mesoscopic, and macroscopic scales by using infrared spectroscopy (IR), scanning electron microscope (SEM), and Zeta potential tests, respectively. Based on these tests, reasons for variations in modification effects of different slurries are identified. The results show that addition of 3 % sodium carbonate to the silty clay can effectively improve the rheological properties of the slurry. The modification mechanism of sodium carbonate involves the formation of hydrogen bonds between water molecules and inner surface hydroxyl groups within the lattice layer of kaolinite. This process significantly enhances the rheological properties of the silty clay slurry. Furthermore, sodium carbonate alters the contact relationships between the silty clay particles, which increases viscosity and reduces permeability of the slurry. Finally, sodium carbonate increases thickness of the electrical double layer of the silty clay particles. This allows the particles to bind more water molecules, therefore improving slurry-making capacity of the silty clay. This paper presents an innovative multiscale analysis of the modification process of silty clay. The substitution of recycled silty clay for bentonite as a slag conditioner not only substantially reduces the cost of purchasing materials, but also considerably decreases the expenses associated with transportation and disposal of the soil discharged by EPBS.