Strategies on utilizing biomass derived 5-hydroxymethylfufural by catalytic reactions: Pathways and mechanisms

IF 7.1 3区材料科学 Q1 GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY

Materials Today Sustainability Pub Date : 2024-12-05 DOI:10.1016/j.mtsust.2024.101058

Serin Jung , Kyung Suh Kim , Geon Hyeong Park , Hyun Gil Cha , Hanseob Jeong , Myung Jong Kang

{"title":"Strategies on utilizing biomass derived 5-hydroxymethylfufural by catalytic reactions: Pathways and mechanisms","authors":"Serin Jung , Kyung Suh Kim , Geon Hyeong Park , Hyun Gil Cha , Hanseob Jeong , Myung Jong Kang","doi":"10.1016/j.mtsust.2024.101058","DOIUrl":null,"url":null,"abstract":"<div><div>Biomass refinery, produces chemicals that can replace pristine petroleum-derived chemicals through chemical/biological engineering processes, and is regarded as a renewable energy source for achieving environmental-friendly production and sustainability. Among various kinds of biomass derived chemicals, 5-hydroxymethylfufural (5-HMF), produced by the dehydration of fructose via glucose isomerization, has remarkable potential as a platform chemical for utilization in value-added products such as pharmaceutical, bio plastics, bio fuels and polyesters. Representative chemicals produced from 5-HMF are 2,5-diformylfuran and 2,5-furandicarboxylic acid, which are generated via oxidation reactions, and 2,5-bis(hydroxymethyl)furan which are generated via a reduction reaction. Theses oxidation/reduction products can potentially be used as value-added chemicals for polymer vitrimers, and in bioplastic monomers for replacing pristine polyethylene terephthalate, polyurethane and polyesters. Herein, the recent achievements in the catalytic conversion of 5-HMF to oxidation/reduction products using heterogeneous catalysts and electrocatalysts are presented, including the detailed catalytic mechanisms of 5-HMF valorization. The current challenges and future perspectives are discussed to prompt further studies and catalyst design for the oxidation/reduction of 5-HMF to useful chemicals.</div></div>","PeriodicalId":18322,"journal":{"name":"Materials Today Sustainability","volume":"29 ","pages":"Article 101058"},"PeriodicalIF":7.1000,"publicationDate":"2024-12-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Today Sustainability","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2589234724003944","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY","Score":null,"Total":0}

引用次数: 0

Abstract

Biomass refinery, produces chemicals that can replace pristine petroleum-derived chemicals through chemical/biological engineering processes, and is regarded as a renewable energy source for achieving environmental-friendly production and sustainability. Among various kinds of biomass derived chemicals, 5-hydroxymethylfufural (5-HMF), produced by the dehydration of fructose via glucose isomerization, has remarkable potential as a platform chemical for utilization in value-added products such as pharmaceutical, bio plastics, bio fuels and polyesters. Representative chemicals produced from 5-HMF are 2,5-diformylfuran and 2,5-furandicarboxylic acid, which are generated via oxidation reactions, and 2,5-bis(hydroxymethyl)furan which are generated via a reduction reaction. Theses oxidation/reduction products can potentially be used as value-added chemicals for polymer vitrimers, and in bioplastic monomers for replacing pristine polyethylene terephthalate, polyurethane and polyesters. Herein, the recent achievements in the catalytic conversion of 5-HMF to oxidation/reduction products using heterogeneous catalysts and electrocatalysts are presented, including the detailed catalytic mechanisms of 5-HMF valorization. The current challenges and future perspectives are discussed to prompt further studies and catalyst design for the oxidation/reduction of 5-HMF to useful chemicals.

Abstract Image

查看原文本刊更多论文

求助全文

约1分钟内获得全文求助全文

来源期刊

Materials Today Sustainability Multiple-

CiteScore

5.80

自引率

6.40%

发文量

174

审稿时长

32 days

期刊介绍： Materials Today Sustainability is a multi-disciplinary journal covering all aspects of sustainability through materials science. With a rapidly increasing population with growing demands, materials science has emerged as a critical discipline toward protecting of the environment and ensuring the long term survival of future generations.