Electrochemical behaviour of amodiaquine detection using boron doped diamond electrodes

IF 1.3 4区 化学 Q4 ELECTROCHEMISTRY
Muhammad Raihan Ramadhan , Keysi Devain Destiny , Meutya Dwi Leoriza , Nessa Sabriena , Fredy Kurniawan , Andi Idhil Ismail , Murni Handayani , Genki Ogata , Yasuaki Einaga , Yunita Triana
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引用次数: 0

Abstract

In this study, we propose a simple and low-cost procedure by using boron-doped diamond (BDD) as a working electrode to detect amodiaquine (AQ) in phosphate buffer solution (PBS) and potassium perchlorate (KClO4) electrolytes. We used cyclic voltammetry (CV) and different pulse voltammetry (DPV) techniques. By using DPV, oxidation of AQ in PBS and KClO4 was observed at + 0.28 V and + 0.4 V (vs. Ag/AgCl), respectively. To investigate the redox reaction mechanism, the pH and scan rate were varied. A linear calibration curve was observed in the concentration range of 0.0645 – 0.3 µM with a detection limit of 1.47 × 10−3 µM (S/N = 3) for PBS and 4.81 × 10−3 µM (S/N = 3) for KClO4. This result confirms that BDD electrodes could potentially be used to detect AQ.
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来源期刊
CiteScore
3.00
自引率
20.00%
发文量
714
审稿时长
2.6 months
期刊介绍: International Journal of Electrochemical Science is a peer-reviewed, open access journal that publishes original research articles, short communications as well as review articles in all areas of electrochemistry: Scope - Theoretical and Computational Electrochemistry - Processes on Electrodes - Electroanalytical Chemistry and Sensor Science - Corrosion - Electrochemical Energy Conversion and Storage - Electrochemical Engineering - Coatings - Electrochemical Synthesis - Bioelectrochemistry - Molecular Electrochemistry
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