Two-dimensional electrode material for (photo)electrochemical reduction of CO2: An overview

Abstract

Human-induced global warming poses one of the most urgent and critical challenges to our planet's atmosphere, ecosystems, and overall well-being. To combat this, we must focus on reducing our reliance on fossil fuels, thereby leading to a consequent decrease in atmospheric CO₂ levels. However, the endeavour to curb CO₂ emissions is riddled with obstacles, including sluggish kinetic reactions of the CO₂ conversion process and poor selectivity of the conventional methods. In addition, detecting CO₂ products and intermediates on a small scale presents a notable challenge within this field. The minute quantity of the CO₂ product has the potential to undergo further oxidation or evaporation, thereby complicating the detection process. Within the realm of CO₂ reduction methods, the photoelectrochemical (PEC) CO₂ conversion technique emerges as highly promising and feasible. This method facilitates precise control over the thermodynamics and kinetics of the CO₂ reduction process, thereby enabling improved product selectivity and accelerated reaction kinetics. Its emulation of natural photosynthesis with minimal energy input elevates its potential for widespread adoption. Nevertheless, there are certain limitations currently hindering its widespread application. In contrast, in recent years, 2D electrode materials have demonstrated promising results for PEC CO₂ conversion. The distinct mechanical, physical, and electrochemical properties of 2D materials hold significant promise as novel catalysts for CO₂ reduction. Furthermore, modifying the 2D electrode surface through techniques such as spin-coating, sputter coating, electrophoretic deposition, and electrochemical means can substantially enhance CO₂ reduction and facilitate the production of valuable by-products. These 2D-based composite materials present an innovative perspective, encapsulating their performance and the inherent challenges of this pioneering field.