Experimental study on seepage–corrosion coupling characteristics of a single fracture in limestone subjected to acid mine drainage

IF 3.3 2区 工程技术 Q3 ENERGY & FUELS
Jing Liu , Shuangying Zuo , Yunchuan Mo
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Abstract

To investigate the influences of the acid mine drainage (AMD) in a closed coal mine on the corrosion and seepage stability of limestone with rough fractures, both distilled water and AMD solution were employed to implement seepage-corrosion tests on the seven sets of a single fracture of limestone specimens under different hydraulic conditions. We investigated the effects of confining stress and solution on the seepage parameters. Also, the mechanism of seepage reduction of fractured limestone caused by AMD solution was proposed. Moreover, COMSOL numerical software was used to simulate the chemical-seepage coupling field characteristics of a rough fracture under condition 4. The results are as follows: (1) The permeability, the Ca2+ concentration gradually decreases, and the osmotic stress, the total iron concentration gradually increases during the seepage process. (2) Differences between the bedding and matrix corrosion exist, the roughness of the fracture surface decreases, and “passivation” occurs on the surface, which makes the permeability decrease rapidly in the early stages and stabilize later. (3) The real-time permeability of fractured limestone under high confining stress is smaller than that under low confining stress and the sensitivity of permeability decreased with the increase of confining stress. (4) The numerical simulated results show the diffusion area of the solution on the fracture wall expands with increasing seepage-corrosion time and osmotic stress of the entrance section. This work will be of great significance to guide the treatment of AMD and the stability analysis of engineering rock masses.
酸性矿井水作用下石灰岩单裂隙渗流-腐蚀耦合特性试验研究
为研究密闭煤矿酸性矿井水(AMD)对粗缝石灰岩腐蚀和渗流稳定性的影响,采用蒸馏水和AMD溶液对不同水力条件下7组单缝石灰岩试样进行了渗透腐蚀试验。研究了围应力和溶液对渗流参数的影响。并提出了AMD溶液对裂隙灰岩的减渗机理。利用COMSOL数值模拟软件模拟了条件4下粗裂缝的化学渗流耦合场特征。结果表明:(1)渗透过程中渗透性、Ca2+浓度逐渐降低,渗透应力、总铁浓度逐渐升高。(2)层理腐蚀与基体腐蚀存在差异,裂缝表面粗糙度降低,表面发生“钝化”,使得渗透率前期迅速下降,后期趋于稳定。(3)裂隙灰岩在高围应力条件下的实时渗透率小于低围应力条件下,渗透率敏感性随围应力的增大而降低。(4)数值模拟结果表明,随着渗透腐蚀时间的延长和入口段渗透应力的增大,溶液在裂缝壁上的扩散面积增大。该工作对指导AMD的处理和工程岩体的稳定性分析具有重要意义。
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来源期刊
Geomechanics for Energy and the Environment
Geomechanics for Energy and the Environment Earth and Planetary Sciences-Geotechnical Engineering and Engineering Geology
CiteScore
5.90
自引率
11.80%
发文量
87
期刊介绍: The aim of the Journal is to publish research results of the highest quality and of lasting importance on the subject of geomechanics, with the focus on applications to geological energy production and storage, and the interaction of soils and rocks with the natural and engineered environment. Special attention is given to concepts and developments of new energy geotechnologies that comprise intrinsic mechanisms protecting the environment against a potential engineering induced damage, hence warranting sustainable usage of energy resources. The scope of the journal is broad, including fundamental concepts in geomechanics and mechanics of porous media, the experiments and analysis of novel phenomena and applications. Of special interest are issues resulting from coupling of particular physics, chemistry and biology of external forcings, as well as of pore fluid/gas and minerals to the solid mechanics of the medium skeleton and pore fluid mechanics. The multi-scale and inter-scale interactions between the phenomena and the behavior representations are also of particular interest. Contributions to general theoretical approach to these issues, but of potential reference to geomechanics in its context of energy and the environment are also most welcome.
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