Automated Investigation of Metal-Ligand Interactions by a Newly Established Robotic Workflow for Titrations

IF 2.8 4区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

ChemPlusChem Pub Date : 2025-02-03 DOI:10.1002/cplu.202400686

Michael Ringleb, Lukas Klähn, Stefan Zechel, Ulrich S. Schubert

引用次数: 0

Abstract

In this work, we present a new workflow to set up an automated platform for the investigation of metal complex formation in solutions. With the utilization of this robot titration platform, the generation of an abundancy of solvated metal complexes in differing coordination number is possible in a simple manner. The generated complexes can subsequently be sampled into differing vessels to examine them in detail. We present sampling for UV/Vis and NMR spectroscopy at chosen model systems, however, the platform can easily be adapted to provide samples for other techniques, e. g., for infrared spectroscopy.

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通过新建立的滴定机器人工作流程自动研究金属-配体相互作用。

在这项工作中，我们提出了一种新的工作流程来建立一个自动化的平台，用于研究溶液中金属络合物的形成。利用该机器人滴定平台，可以简单地生成丰度不同配位数的溶剂化金属配合物。生成的复合物随后可以被取样到不同的血管中以详细检查它们。我们在选定的模型系统上为紫外/可见和核磁共振光谱提供采样，然而，该平台可以很容易地适应为其他技术提供样品，例如红外光谱。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

ChemPlusChem CHEMISTRY, MULTIDISCIPLINARY-

CiteScore

5.90

自引率

0.00%

发文量

200

审稿时长

1 months

期刊介绍： ChemPlusChem is a peer-reviewed, general chemistry journal that brings readers the very best in multidisciplinary research centering on chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies. Fully comprehensive in its scope, ChemPlusChem publishes articles covering new results from at least two different aspects (subfields) of chemistry or one of chemistry and one of another scientific discipline (one chemistry topic plus another one, hence the title ChemPlusChem). All suitable submissions undergo balanced peer review by experts in the field to ensure the highest quality, originality, relevance, significance, and validity.