Origin of Ultrapotassic, Ultracalcic, Ultrabasic SiO2-Undersaturated Magmas: The Case Study of the Pleistocene Cupaello Kamafugite Monogenetic Volcano, Central Italy

IF 2.9 2区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS
Michele Lustrino, Lorenzo Pistocchi, Sara Ronca, Francesca Innocenzi, Samuele Agostini
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Abstract

The Pleistocene (∼0.6 Ma) Cupaello monogenetic volcano, cropping out in central Italy, belongs to the Intra Apennine Province (IAP). It is represented by a single lava flow with kamafugitic composition, associated with a volumetrically limited pyroclastic deposit and a phosphate-rich layer close to the small vent. This kamafugite is characterized by ultrapotassic (K2O = 5.2–7.6 mass %; K2O/Na2O = 18.0–33.9), ultracalcic (CaO/Al2O3 = 2.2–2.4), ultrabasic (SiO2 = 42.6–44.1 mass %), and SiO2-undersaturated (∼29% CIPW normative leucite) composition, with a peculiar paragenesis (kalsilite, melilite, phlogopite, clinopyroxene, calcite, olivine and glass, plus accessory phases). Trace elements (e.g., high LILE, high LILE/HFSE, negative anomalies for Nb, Ta, Ti and Eu, and Pb peaks in primitive mantle-normalized diagrams) and isotopic constraints (e.g., strongly radiogenic 87Sr/86Sr, unradiogenic 143Nd/144Nd, high Δ7/4) point to subduction-modified mantle sources. Cupaello products fall within the field of the IAP volcanic products, which define, as a whole, clear negative correlations of compatible and incompatible trace elements, as well as of all the other major oxides, with CaO. These trends are here interpreted as the effect of assimilation of crustal carbonates rather than the presence of a Ca-carbonatitic component in the source, as instead commonly reported in literature. Despite this general trend, we emphasize that Cupaello rocks derive from partial melting of a subduction-modified carbonated phlogopite-peridotite source, followed by a prolonged fractional crystallization of olivine- and melilite-rich kalsilitolite assemblages. A carbonatitic component is required to explain the absence of feldspars in the ultrabasic, ultracalcic and strongly SiO2-undersaturated magma, whose composition was possibly modified in minimal amounts by carbonate assimilation at shallow depths.

Abstract Image

超寒武纪、超钙质、超基性sio2欠饱和岩浆的成因——以意大利中部更新世Cupaello kamafuite单成因火山为例
位于意大利中部的更新世(~ 0.6 Ma) Cupaello单成因火山,属于亚平宁省内(IAP)。它以单一的熔岩流为代表,具有kamafutic成分,与体积有限的火山碎屑矿床和靠近小喷口的富磷酸盐层有关。该kamafuite的特征为超经典(K2O = 5.2 ~ 7.6质量%;K2O/Na2O = 18.0-33.9)、超碱性(CaO/Al2O3 = 2.2-2.4)、超碱性(SiO2 = 42.6-44.1质量%)和SiO2欠饱和(~ 29% CIPW标准白晶石)组成,具有特殊的共生(千硅石、千硅石、辉云母、斜辉石、方解石、橄榄石和玻璃,以及辅助相)。微量元素(如高LILE、高LILE/HFSE、原始地幔归一化图中Nb、Ta、Ti、Eu负异常、Pb峰)和同位素约束(如强放射性87Sr/86Sr、非放射性143Nd/144Nd、高Δ7/4)指向俯冲修饰的地幔源。Cupaello产物属于IAP火山产物的范畴,整体上定义了相容和不相容微量元素以及所有其他主要氧化物与CaO的明显负相关关系。这些趋势在这里被解释为地壳碳酸盐同化的影响,而不是像文献中普遍报道的那样,在来源中存在钙-碳酸盐成分。尽管有这种总体趋势,但我们强调,Cupaello岩石起源于俯冲修饰的碳酸化辉云母-橄榄岩源的部分熔融,随后是富含橄榄石和千英石的千英石组合的长时间分离结晶。在超基性、超钙性和强sio2欠饱和岩浆中没有长石,需要用碳酸盐岩成分来解释,这些岩浆的成分可能在浅层碳酸盐同化作用下发生了少量的改变。
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来源期刊
Geochemistry Geophysics Geosystems
Geochemistry Geophysics Geosystems 地学-地球化学与地球物理
CiteScore
5.90
自引率
11.40%
发文量
252
审稿时长
1 months
期刊介绍: Geochemistry, Geophysics, Geosystems (G3) publishes research papers on Earth and planetary processes with a focus on understanding the Earth as a system. Observational, experimental, and theoretical investigations of the solid Earth, hydrosphere, atmosphere, biosphere, and solar system at all spatial and temporal scales are welcome. Articles should be of broad interest, and interdisciplinary approaches are encouraged. Areas of interest for this peer-reviewed journal include, but are not limited to: The physics and chemistry of the Earth, including its structure, composition, physical properties, dynamics, and evolution Principles and applications of geochemical proxies to studies of Earth history The physical properties, composition, and temporal evolution of the Earth''s major reservoirs and the coupling between them The dynamics of geochemical and biogeochemical cycles at all spatial and temporal scales Physical and cosmochemical constraints on the composition, origin, and evolution of the Earth and other terrestrial planets The chemistry and physics of solar system materials that are relevant to the formation, evolution, and current state of the Earth and the planets Advances in modeling, observation, and experimentation that are of widespread interest in the geosciences.
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