A high-entropy (Er0.25Y0.25Ho0.25Yb0.25)2Si2O7 ceramic with good thermal properties and water-vapor corrosion resistance

IF 1.8 4区 材料科学 Q2 MATERIALS SCIENCE, CERAMICS
Bingqing Zhao, Wei Xie, Hailong Wang, Jinpeng Zhu, Mingliang Li, Bei Cai
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引用次数: 0

Abstract

A high-entropy rare-earth disilicate (Er0.25Y0.25Ho0.25Yb0.25)2Si2O7 (hereinafter referred to as (EYHY)2Si2O7) ceramic was synthesized by a heat treatment process combined with spark plasma sintering. According to the experimental results, (EYHY)2Si2O7 presents good phase stability and low thermal conductivity ([1.48–2.35] W∙m−1∙K−1) from room temperature to 1200°C. Its coefficient of thermal expansion is (3.89–5.32) × 10−6 K−1 from 200 to 1400°C, similar to SiC-based materials ([4.5–5.5] × 10−6 K−1). Due to the multiple doping effects, (EYHY)2Si2O7 exhibits outstanding corrosion resistance performance in water-vapor corrosion tests. Its weight loss is 1.79 mg/cm2 after corrosion at 1600°C for 30 h in the presence of 50% H2O-50% O2, which is lower than the corresponding four single components Re2Si2O7 (Er2Si2O7, Y2Si2O7, Ho2Si2O7, and Yb2Si2O7) under the same conditions. Therefore, high-entropy (EYHY)2Si2O7 ceramics are regarded as potential environmental barrier coatings materials for SiC ceramic matrix composites.

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来源期刊
International Journal of Applied Ceramic Technology
International Journal of Applied Ceramic Technology 工程技术-材料科学:硅酸盐
CiteScore
3.90
自引率
9.50%
发文量
280
审稿时长
4.5 months
期刊介绍: The International Journal of Applied Ceramic Technology publishes cutting edge applied research and development work focused on commercialization of engineered ceramics, products and processes. The publication also explores the barriers to commercialization, design and testing, environmental health issues, international standardization activities, databases, and cost models. Designed to get high quality information to end-users quickly, the peer process is led by an editorial board of experts from industry, government, and universities. Each issue focuses on a high-interest, high-impact topic plus includes a range of papers detailing applications of ceramics. Papers on all aspects of applied ceramics are welcome including those in the following areas: Nanotechnology applications; Ceramic Armor; Ceramic and Technology for Energy Applications (e.g., Fuel Cells, Batteries, Solar, Thermoelectric, and HT Superconductors); Ceramic Matrix Composites; Functional Materials; Thermal and Environmental Barrier Coatings; Bioceramic Applications; Green Manufacturing; Ceramic Processing; Glass Technology; Fiber optics; Ceramics in Environmental Applications; Ceramics in Electronic, Photonic and Magnetic Applications;
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