{"title":"Microwave dielectric properties of Na2O–Ln2O3–MoO3–TiO2 (Ln = Nd, La and Ce) system with low-sintering temperature","authors":"Wen-Bo Li, Li-Xia Pang, Xiao-Long Wang, Wei-Guo Liu, Xiaogang Yao, Huixing Lin, Wen-Feng Liu, Di Zhou","doi":"10.1111/ijac.14983","DOIUrl":null,"url":null,"abstract":"<p>This study examines the low-loss and temperature-stable Na<sub>2</sub>O–Ln<sub>2</sub>O<sub>3</sub>–MoO<sub>3</sub>–TiO<sub>2</sub> (Ln = Nd, La and Ce) system, synthesized via a solid-state process at low-sintering temperatures ranging from 840°C to 900°C The structure, microstructure and microwave properties of the Na<sub>0.5</sub>Ln<sub>0.5</sub>MoO<sub>4</sub>–TiO<sub>2</sub> (Ln = Nd, La and Ce) ceramics as a function of the sintering temperature were studied. The results of XRD patterns and microstructure characterization showed that the main phase in compositions belong to tetragonal scheelite and tetragonal structure. The ceramic composition Na<sub>0.5</sub>Ln<sub>0.5</sub>MoO<sub>4</sub>–TiO<sub>2</sub> (Ln = Nd, La and Ce), sintered at 840°C–900°C for 2 hours, demonstrated excellent microwave dielectric properties, exhibiting relative dielectric constant (<i>ε<sub>r</sub></i>) of 13.9–14.4, <i>Q × f</i> value of about 31 100 (at 9.66 GHz) – 48 600 GHz (at 9.33 GHz), and temperature coefficient of –8.1 to –1 ppm/°C. Our work designs temperature-stable microwave dielectric ceramics with low-sintering temperature for LTCC technology applications.</p>","PeriodicalId":13903,"journal":{"name":"International Journal of Applied Ceramic Technology","volume":"22 2","pages":""},"PeriodicalIF":1.8000,"publicationDate":"2024-11-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Applied Ceramic Technology","FirstCategoryId":"88","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1111/ijac.14983","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, CERAMICS","Score":null,"Total":0}
引用次数: 0
Abstract
This study examines the low-loss and temperature-stable Na2O–Ln2O3–MoO3–TiO2 (Ln = Nd, La and Ce) system, synthesized via a solid-state process at low-sintering temperatures ranging from 840°C to 900°C The structure, microstructure and microwave properties of the Na0.5Ln0.5MoO4–TiO2 (Ln = Nd, La and Ce) ceramics as a function of the sintering temperature were studied. The results of XRD patterns and microstructure characterization showed that the main phase in compositions belong to tetragonal scheelite and tetragonal structure. The ceramic composition Na0.5Ln0.5MoO4–TiO2 (Ln = Nd, La and Ce), sintered at 840°C–900°C for 2 hours, demonstrated excellent microwave dielectric properties, exhibiting relative dielectric constant (εr) of 13.9–14.4, Q × f value of about 31 100 (at 9.66 GHz) – 48 600 GHz (at 9.33 GHz), and temperature coefficient of –8.1 to –1 ppm/°C. Our work designs temperature-stable microwave dielectric ceramics with low-sintering temperature for LTCC technology applications.
期刊介绍:
The International Journal of Applied Ceramic Technology publishes cutting edge applied research and development work focused on commercialization of engineered ceramics, products and processes. The publication also explores the barriers to commercialization, design and testing, environmental health issues, international standardization activities, databases, and cost models. Designed to get high quality information to end-users quickly, the peer process is led by an editorial board of experts from industry, government, and universities. Each issue focuses on a high-interest, high-impact topic plus includes a range of papers detailing applications of ceramics. Papers on all aspects of applied ceramics are welcome including those in the following areas:
Nanotechnology applications;
Ceramic Armor;
Ceramic and Technology for Energy Applications (e.g., Fuel Cells, Batteries, Solar, Thermoelectric, and HT Superconductors);
Ceramic Matrix Composites;
Functional Materials;
Thermal and Environmental Barrier Coatings;
Bioceramic Applications;
Green Manufacturing;
Ceramic Processing;
Glass Technology;
Fiber optics;
Ceramics in Environmental Applications;
Ceramics in Electronic, Photonic and Magnetic Applications;