Copper-Catalyzed Ring-Opening Hydrosilylation and Hydroboration of Arylidenecyclopropanes

IF 5.5 1区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chinese Journal of Chemistry Pub Date : 2024-11-11 DOI:10.1002/cjoc.202400811

Zhen-Yu Xiao, Zi-Lu Wang, Yun-He Xu

引用次数: 0

Abstract

Arylidenecyclopropanes (ACPs) are highly strained substrates that can be readily utilized for diverse transformations. This study showcases the outcomes of copper-catalyzed ring-opening hydrosilylation and hydroboration reactions of ACPs, showcasing precise cleavage of C—C bonds. The reaction presents an effective and convenient method for producing homoallylic silanes and boronates.

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来源期刊

Chinese Journal of Chemistry 化学-化学综合

CiteScore

8.80

自引率

14.80%

发文量

422

审稿时长

1.7 months

期刊介绍： The Chinese Journal of Chemistry is an international forum for peer-reviewed original research results in all fields of chemistry. Founded in 1983 under the name Acta Chimica Sinica English Edition and renamed in 1990 as Chinese Journal of Chemistry, the journal publishes a stimulating mixture of Accounts, Full Papers, Notes and Communications in English.