Strategies to increase catalytic efficiency of manganese-catalyzed aerobic oxidation of 5-hydroxymethylfurfural

IF 1.7 4区化学

Bulletin of the Korean Chemical Society Pub Date : 2024-12-12 DOI:10.1002/bkcs.12925

Hyejin Yu, Yeonkyeong Ryu, Younghoon Kim, Hyun Sung Kim, Hyun Gil Cha

引用次数: 0

Abstract

The aerobic oxidation of 5-hydroxymethylfurfural (HMF) into 2,5-furandicarboxylic acid (FDCA), a bio-based plastic monomer, is an important process for the valorization of biomass. Here, manganese oxides of various oxidation states with identical morphologies and similar surface areas were synthesized by introducing oxygen vacancy sites, and they were investigated as heterogeneous catalysts for HMF oxidation. Mn₂O₃ exhibited a remarkable catalytic efficiency due to synergistic effect of the oxidation state of metal moieties, the basicity of the catalyst, and oxygen mobility of the oxide materials under basic condition.

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来源期刊

Bulletin of the Korean Chemical Society Chemistry-General Chemistry

自引率

23.50%

发文量

182

期刊介绍： The Bulletin of the Korean Chemical Society is an official research journal of the Korean Chemical Society. It was founded in 1980 and reaches out to the chemical community worldwide. It is strictly peer-reviewed and welcomes Accounts, Communications, Articles, and Notes written in English. The scope of the journal covers all major areas of chemistry: analytical chemistry, electrochemistry, industrial chemistry, inorganic chemistry, life-science chemistry, macromolecular chemistry, organic synthesis, non-synthetic organic chemistry, physical chemistry, and materials chemistry.