{"title":"Morphological and Conductivity Studies of Fullerene (C60) and N-Vinyl Carbazole Based Interpenetrating Polymer Network","authors":"Mohd. Meraj Jafri, Meet Kamal","doi":"10.1134/S107042722407005X","DOIUrl":null,"url":null,"abstract":"<p>In the present study we have synthesized interpenetrating polymer network (IPN) of fullerene (C<sub>60</sub>) and <i>N</i>-vinyl carbazole (NVC). The IPNFC was characterized using infrared (IR) spectroscopy, scanning electron microscope (SEM) and conductivity techniques which reveals desirable and interesting results. IR spectroscopy reveals presence of fullerene at 527 and 1600 cm<sup>–1</sup> and poly (<i>N</i>-vinyl carbazole) at 1101 cm<sup>–1</sup>. A thin polymeric interconnected film is seen via SEM technique, revealing transparent and dual phase morphology. IPN is also analyzed for permeability and permittivity, which reveals maximum value of ε<sub>r</sub>', ε<sub>r</sub>'' and tan δ<sub>ε</sub> at 2.77, 0.48, and 0.11, respectively, and maximum values of μ'<sub>r</sub> of μ''<sub>r</sub>, and tan μ <sub>r</sub> ranging from 0.99 to 1.50, 0.01–0.103, and 0.01–0.08, respectively. Moderate values of permeability and permittivity reveals electromagnetic property of the IPN. Conductivity IPN was calculated and found to be 4.98 S/m, which describes the semiconducting nature of the polymeric network.</p>","PeriodicalId":757,"journal":{"name":"Russian Journal of Applied Chemistry","volume":"97 7","pages":"623 - 628"},"PeriodicalIF":0.6000,"publicationDate":"2025-01-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Applied Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S107042722407005X","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, APPLIED","Score":null,"Total":0}
引用次数: 0
Abstract
In the present study we have synthesized interpenetrating polymer network (IPN) of fullerene (C60) and N-vinyl carbazole (NVC). The IPNFC was characterized using infrared (IR) spectroscopy, scanning electron microscope (SEM) and conductivity techniques which reveals desirable and interesting results. IR spectroscopy reveals presence of fullerene at 527 and 1600 cm–1 and poly (N-vinyl carbazole) at 1101 cm–1. A thin polymeric interconnected film is seen via SEM technique, revealing transparent and dual phase morphology. IPN is also analyzed for permeability and permittivity, which reveals maximum value of εr', εr'' and tan δε at 2.77, 0.48, and 0.11, respectively, and maximum values of μ'r of μ''r, and tan μ r ranging from 0.99 to 1.50, 0.01–0.103, and 0.01–0.08, respectively. Moderate values of permeability and permittivity reveals electromagnetic property of the IPN. Conductivity IPN was calculated and found to be 4.98 S/m, which describes the semiconducting nature of the polymeric network.
期刊介绍:
Russian Journal of Applied Chemistry (Zhurnal prikladnoi khimii) was founded in 1928. It covers all application problems of modern chemistry, including the structure of inorganic and organic compounds, kinetics and mechanisms of chemical reactions, problems of chemical processes and apparatus, borderline problems of chemistry, and applied research.