Verification and Spectral Separation of Up-Conversion Processes in Fluorophosphate Glass Doped with Ytterbium and Thulium Ions Based on the Dependence of Their Effective Nonlinearity on Wavelength

IF 0.8 4区化学 Q4 SPECTROSCOPY

Journal of Applied Spectroscopy Pub Date : 2025-01-09 DOI:10.1007/s10812-025-01839-8

M. V. Korolkov, I. A. Khodasevich, A. S. Grabtchikov, G. Munkhbayar, D. S. Mogilevtsev

{"title":"Verification and Spectral Separation of Up-Conversion Processes in Fluorophosphate Glass Doped with Ytterbium and Thulium Ions Based on the Dependence of Their Effective Nonlinearity on Wavelength","authors":"M. V. Korolkov, I. A. Khodasevich, A. S. Grabtchikov, G. Munkhbayar, D. S. Mogilevtsev","doi":"10.1007/s10812-025-01839-8","DOIUrl":null,"url":null,"abstract":"<p>Up-conversion luminescence (UCL) spectra of fluorophosphate glasses doped with the pair of rare-earth ions (REIs) ytterbium (4%) and thulium (0.1%) excited by radiation of a diode laser operating in steady-state mode at wavelength 975 nm are studied. Each of the observed UCL bands is a result of manifestation of several up-conversion processes (UCPs) corresponding to luminescence of thulium ions from different excited states. These UCPs are characterized by different degrees of effective nonlinearity (EN). The effect of pump power on UCL spectra formed by UCPs with different ENs is studied. The possibility of separation of spectra corresponding to individual UCPs from the total experimentally measured UCL spectrum of fluorophosphate glass doped with the pair of REIs ytterbium (4%) and thulium (0.1%) is demonstrated. The separation is based on the calculation of the EN based on the dependences of the UCL on the excitation power.</p>","PeriodicalId":609,"journal":{"name":"Journal of Applied Spectroscopy","volume":"91 6","pages":"1209 - 1219"},"PeriodicalIF":0.8000,"publicationDate":"2025-01-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Applied Spectroscopy","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s10812-025-01839-8","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"SPECTROSCOPY","Score":null,"Total":0}

引用次数: 0

Abstract

Up-conversion luminescence (UCL) spectra of fluorophosphate glasses doped with the pair of rare-earth ions (REIs) ytterbium (4%) and thulium (0.1%) excited by radiation of a diode laser operating in steady-state mode at wavelength 975 nm are studied. Each of the observed UCL bands is a result of manifestation of several up-conversion processes (UCPs) corresponding to luminescence of thulium ions from different excited states. These UCPs are characterized by different degrees of effective nonlinearity (EN). The effect of pump power on UCL spectra formed by UCPs with different ENs is studied. The possibility of separation of spectra corresponding to individual UCPs from the total experimentally measured UCL spectrum of fluorophosphate glass doped with the pair of REIs ytterbium (4%) and thulium (0.1%) is demonstrated. The separation is based on the calculation of the EN based on the dependences of the UCL on the excitation power.

查看原文本刊更多论文

求助全文

约1分钟内获得全文求助全文

来源期刊

Journal of Applied Spectroscopy SPECTROSCOPY-

CiteScore

1.30

自引率

14.30%

发文量

145

审稿时长

2.5 months

期刊介绍： Journal of Applied Spectroscopy reports on many key applications of spectroscopy in chemistry, physics, metallurgy, and biology. An increasing number of papers focus on the theory of lasers, as well as the tremendous potential for the practical applications of lasers in numerous fields and industries.