Parastoo Arman Nezhad, Farzad Dabirian, Ali Ashraf Derakhshan, Laleh Rajabi, Sepide Heydari, Ali Rostami
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引用次数: 0
Abstract
This study details the preparation and evaluation of a nanofibrous composite adsorbent comprising polyacrylonitrile (PAN) as the polymer matrix and Schiff-base alumoxane (SBA), designed for the adsorption of heavy metal cations Pb2⁺ and Cd2⁺. The nanofibrous structure provides an extensive surface area for effective adsorption. Key factors such as solution pH, nanoparticle concentration, initial ion concentration, and contact time were systematically examined using response surface methodology (RSM) within a central composite design (CCD). The SBA/PAN nanocomposite nanofibers were synthesized through an electrospinning process, followed by a dip-coating technique, and subsequently characterized for their adsorption capabilities. The statistical analysis revealed that the model terms significantly influenced the adsorption process, with "Prob > F" values much less than 0.0500. The optimization of the process, achieved through the response surface optimization technique, led to a maximum removal efficiency of 97.22% for Pb2⁺ and 93.87% for Cd2⁺ under optimal conditions: initial ion concentration of 36.87 ppm, nanoparticle concentration of 4.02 wt.%, pH of 6.40, and a contact time of 69.11 min. Adsorption capacities of 35.84 mg/g for Pb2⁺ and 34.61 mg/g for Cd2⁺ were observed under these conditions. Reanalysis of isothermic and kinetic data confirmed Langmuir for Pb2⁺ and for Cd2⁺, with pseudo-second-order kinetics (R2 > 0.99) indicating chemisorption as the dominant mechanism. These findings demonstrate the potential of SBA/PAN nanocomposite nanofibers as effective adsorbents for heavy metal removal from aqueous solutions.emoval from aqueous solutions.
期刊介绍:
Journal of Polymer Research provides a forum for the prompt publication of articles concerning the fundamental and applied research of polymers. Its great feature lies in the diversity of content which it encompasses, drawing together results from all aspects of polymer science and technology.
As polymer research is rapidly growing around the globe, the aim of this journal is to establish itself as a significant information tool not only for the international polymer researchers in academia but also for those working in industry. The scope of the journal covers a wide range of the highly interdisciplinary field of polymer science and technology, including:
polymer synthesis;
polymer reactions;
polymerization kinetics;
polymer physics;
morphology;
structure-property relationships;
polymer analysis and characterization;
physical and mechanical properties;
electrical and optical properties;
polymer processing and rheology;
application of polymers;
supramolecular science of polymers;
polymer composites.