Effect of Structural Defects Induced in LaFeO3 and LaMnO3 Catalysts towards Total Oxidation of 2-Propanol

IF 2.3 4区 化学 Q3 CHEMISTRY, PHYSICAL
Múnera-Jaramillo Jessica, Tapia-P. Juan, Gallego Jaime, Santamaría Alexander
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Abstract

A crucial characteristic of perovskite-like oxides is oxygen mobility, which can be enhanced by inducing structural defects through stoichiometry variations during synthesis, thereby boosting the catalytic activity. This study evaluated the effect of structural modifications of LaFeO3 (LF) and LaMnO3 (LM) perovskites series on the total oxidation of 2-propanol as a VOC model, a well-known organic solvent. These modifications were performed during synthesis by partially removing the B-site cation or by structural doping in the B-site with another cation (Mn for the LF series and Pd for the LM series). Structural characterization was carried out by XRD and Raman spectroscopy, while the bulk and surface chemical composition were assessed by ICP and XPS, respectively. On the other hand, catalytic activity was performed using a reactivity test with the 2-propanol molecule. The CO-TPR and O2-TPD measurements were used to characterize the reducibility of the active phase, and the type of oxygen species present in the sample. The catalytic activity results indicated that the modified perovskites showed a difference of 118 °C and 109 °C in the T95 parameter (Temperature at which the conversion of 2-propanol was 95%) relative to pure LF and LM perovskites, respectively. It was also observed that the inclusion of cationic species with high oxidation states enhances the catalytic properties of the materials not only for the doped perovskites but also for the impregnated ones used for comparison purposes. This research demonstrated that stoichiometric variations in modified perovskite-like catalysts significantly improve the catalytic capacity by forming structural defects and modifying redox properties.Kindly check and confirm whether the corresponding author is correctly identified.I confirm that the corresponding author is well identified

Graphical Abstract

LaFeO3和LaMnO3催化剂结构缺陷对2-丙醇全氧化的影响
钙钛矿类氧化物的一个重要特征是氧迁移率,在合成过程中通过化学计量变化诱导结构缺陷可以增强氧迁移率,从而提高催化活性。本研究评估了LaFeO3 (LF)和LaMnO3 (LM)钙钛矿系列结构改性对作为VOC模型的2-丙醇总氧化的影响。这些修饰是在合成过程中通过部分去除b位阳离子或在b位上掺杂另一种阳离子(LF系列为Mn, LM系列为Pd)来完成的。采用XRD和拉曼光谱对材料进行了结构表征,采用ICP和XPS分别对材料的体积和表面化学成分进行了表征。另一方面,通过与2-丙醇分子的反应性测试进行了催化活性测试。CO-TPR和O2-TPD测量用于表征活性相的还原性,以及样品中存在的氧气种类。催化活性结果表明,改性钙钛矿的T95参数(2-丙醇转化率为95%的温度)与纯LF钙钛矿和纯LM钙钛矿相比分别相差118℃和109℃。研究还发现,高氧化态阳离子的加入不仅提高了掺杂钙钛矿的催化性能,也提高了浸渍钙钛矿的催化性能。本研究表明,改性类钙钛矿催化剂的化学计量学变化通过形成结构缺陷和改变氧化还原性能显著提高了催化能力。请检查并确认是否正确识别了通讯作者。本人确认通讯作者身份明确
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Catalysis Letters
Catalysis Letters 化学-物理化学
CiteScore
5.70
自引率
3.60%
发文量
327
审稿时长
1 months
期刊介绍: Catalysis Letters aim is the rapid publication of outstanding and high-impact original research articles in catalysis. The scope of the journal covers a broad range of topics in all fields of both applied and theoretical catalysis, including heterogeneous, homogeneous and biocatalysis. The high-quality original research articles published in Catalysis Letters are subject to rigorous peer review. Accepted papers are published online first and subsequently in print issues. All contributions must include a graphical abstract. Manuscripts should be written in English and the responsibility lies with the authors to ensure that they are grammatically and linguistically correct. Authors for whom English is not the working language are encouraged to consider using a professional language-editing service before submitting their manuscripts.
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