Towards outstanding energy-efficiency in a recyclable triboelectric nanogenerator based on a soft-rough composite material

Saisai Hu , Ping Su , Deyin Tao , Luhui Zhu , Aiping Chen , Dawei Gu , Mustafa Eginligil
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Abstract

Energy efficiency vs. degradability of materials making up triboelectric nanogenerators (TENGs) is critical for recyclable energy sources. In this work, we first compared voltage output expectation (Vexp) of contact-separation TENG consisting of two tribo-layers: paper and common plastics used in packaging (both non-biodegradable and biodegradable). Detailed analysis based on atomic force microscopy and capacitance measurements demonstrated surface roughness of soft-rough biodegradable polymers (SRBPs) is expected to yield larger Vexp, predictably. A SRBP composite-based TENG was expected to show ∼7.2 times larger Vexp than a hard-flat nonbiodegradable plastic, demonstrating promising charge transfer efficiency; while the measured voltage (Vmea) was only 6.5% of Vexp. This was unlike the other plastics, including a non-composite SRBP, (Vmea/Vexp ∼0.36) and the low Vmea/Vexp in the SRBP composite-based TENG was attributed to intrinsic material properties. Also, energy conversion efficiency in TENG-based on SRBPs was more than double of hard-flat plastics. This shows the potential of the composite SRBP-based TENG as effective energy harvester.

Abstract Image

基于软粗糙复合材料的可回收摩擦电纳米发电机的卓越能源效率
能源效率与构成摩擦电纳米发电机(TENGs)材料的可降解性是可回收能源的关键。在这项工作中,我们首先比较了由两个摩擦层组成的接触分离TENG的电压输出期望(Vexp):用于包装的纸张和普通塑料(不可生物降解和生物降解)。基于原子力显微镜和电容测量的详细分析表明,软粗糙生物可降解聚合物(srbp)的表面粗糙度有望产生更大的Vexp,这是可以预见的。基于SRBP复合材料的TENG的Vexp预计比硬平面不可生物降解塑料大7.2倍,显示出有希望的电荷转移效率;而测量电压(Vmea)仅为Vexp的6.5%。这与其他塑料不同,包括非复合SRBP, (Vmea/Vexp ~ 0.36)和SRBP复合材料中基于TENG的低Vmea/Vexp归因于固有材料特性。此外,基于SRBPs的teng的能量转换效率是硬平面塑料的两倍多。这显示了基于srbp的复合材料TENG作为有效能量收集器的潜力。
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