Synergetic effect of bimetalic nanoparticles anchored on biomass-derived carbon nanosheets for hydrogen evolution reaction

IF 4.9 2区化学 Q2 CHEMISTRY, PHYSICAL

Colloids and Surfaces A: Physicochemical and Engineering Aspects Pub Date : 2024-12-02 DOI:10.1016/j.colsurfa.2024.135865

Xiaona Zhang , Jingwei Feng , Tuo Yang, Fuming Gao, Zeyang Liu, Chunxia Wang, Guoyong Huang

{"title":"Synergetic effect of bimetalic nanoparticles anchored on biomass-derived carbon nanosheets for hydrogen evolution reaction","authors":"Xiaona Zhang , Jingwei Feng , Tuo Yang, Fuming Gao, Zeyang Liu, Chunxia Wang, Guoyong Huang","doi":"10.1016/j.colsurfa.2024.135865","DOIUrl":null,"url":null,"abstract":"<div><div>Transition metals loaded biomass-derived carbon materials are emerging as a promising cost-effective electrocatalysts for hydrogen evolution reaction (HER). The biomass-derived carbon offers effecient mass transport for gas diffusion while possesses inherit rich porous structure for the disposition of active transition metals. In this work, we demonstrated a facile method to synthesize Co-Ru bimetal supported pine nut shells-derived carbon electrocatalyst (CoRuAC) . The as prepared electrocatalyst shows an unique two-dimensional hierarchical porous structure with uniformly distributed nanoparticles, delivering a low overpotential (160 mV @ 10 mA cm<sup>−2</sup>), small Tafel slope, and long-term stability in alkaline conditions. A series of characterizations revealed that the enhanced HER performance was attributed to the large specific surface area, the mass/charge transfer pathways provided by biomass-derived carbon and the electronic coupling of Co and Ru. This study offers a new inspiration for designing novel and economical electrocatalyst for HER in alkaline electrolytes with green and sustainable strategy.</div></div>","PeriodicalId":278,"journal":{"name":"Colloids and Surfaces A: Physicochemical and Engineering Aspects","volume":"707 ","pages":"Article 135865"},"PeriodicalIF":4.9000,"publicationDate":"2024-12-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Colloids and Surfaces A: Physicochemical and Engineering Aspects","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0927775724027298","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}

引用次数: 0

Abstract

Transition metals loaded biomass-derived carbon materials are emerging as a promising cost-effective electrocatalysts for hydrogen evolution reaction (HER). The biomass-derived carbon offers effecient mass transport for gas diffusion while possesses inherit rich porous structure for the disposition of active transition metals. In this work, we demonstrated a facile method to synthesize Co-Ru bimetal supported pine nut shells-derived carbon electrocatalyst (CoRuAC) . The as prepared electrocatalyst shows an unique two-dimensional hierarchical porous structure with uniformly distributed nanoparticles, delivering a low overpotential (160 mV @ 10 mA cm⁻²), small Tafel slope, and long-term stability in alkaline conditions. A series of characterizations revealed that the enhanced HER performance was attributed to the large specific surface area, the mass/charge transfer pathways provided by biomass-derived carbon and the electronic coupling of Co and Ru. This study offers a new inspiration for designing novel and economical electrocatalyst for HER in alkaline electrolytes with green and sustainable strategy.

查看原文本刊更多论文

求助全文

约1分钟内获得全文求助全文

来源期刊

Colloids and Surfaces A: Physicochemical and Engineering Aspects 化学-物理化学

CiteScore

8.70

自引率

9.60%

发文量

2421

审稿时长

56 days

期刊介绍： Colloids and Surfaces A: Physicochemical and Engineering Aspects is an international journal devoted to the science underlying applications of colloids and interfacial phenomena. The journal aims at publishing high quality research papers featuring new materials or new insights into the role of colloid and interface science in (for example) food, energy, minerals processing, pharmaceuticals or the environment.