Yicheng Tan , Xiuzhen Zhang , Zhichao Liu , Fazhou Wang , Shuguang Hu
{"title":"Dealkalization Behavior and Leaching Mechanisms of Red Mud with Simulated Aluminum Profile Wastewater","authors":"Yicheng Tan , Xiuzhen Zhang , Zhichao Liu , Fazhou Wang , Shuguang Hu","doi":"10.1016/j.dibe.2025.100613","DOIUrl":null,"url":null,"abstract":"<div><div>This study presents a new waste treatment strategy by dealkalizing red mud with simulated aluminum profile wastewater. We investigate the leaching behavior and the effect of the wastewater dropping rate. During dealkalization, the slurry pH significantly decreases while conductivity increases, indicating efficient dealkalization. The increase in Na⁺ in the filtrate and the decrease in Na₂O in the residue confirm the dissolution of alkali, especially structural alkali. The dealkalization efficiency reaches 64.4%. Increasing the dropping rate accelerates the reaction, enhancing efficiency without altering the process. The mechanism involves Al³⁺ combining with hydrolyzed AlO₂⁻ to precipitate Al(OH)₃, effectively removing structural alkali, which is the main restrictive factor in red mud. After dealkalization, the utilization rate of red mud increases from 5% to 15%, positively impacting economic and environmental aspects, particularly land occupation, soil salinization, and human health.</div></div>","PeriodicalId":34137,"journal":{"name":"Developments in the Built Environment","volume":"21 ","pages":"Article 100613"},"PeriodicalIF":6.2000,"publicationDate":"2025-01-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Developments in the Built Environment","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2666165925000134","RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CONSTRUCTION & BUILDING TECHNOLOGY","Score":null,"Total":0}
引用次数: 0
Abstract
This study presents a new waste treatment strategy by dealkalizing red mud with simulated aluminum profile wastewater. We investigate the leaching behavior and the effect of the wastewater dropping rate. During dealkalization, the slurry pH significantly decreases while conductivity increases, indicating efficient dealkalization. The increase in Na⁺ in the filtrate and the decrease in Na₂O in the residue confirm the dissolution of alkali, especially structural alkali. The dealkalization efficiency reaches 64.4%. Increasing the dropping rate accelerates the reaction, enhancing efficiency without altering the process. The mechanism involves Al³⁺ combining with hydrolyzed AlO₂⁻ to precipitate Al(OH)₃, effectively removing structural alkali, which is the main restrictive factor in red mud. After dealkalization, the utilization rate of red mud increases from 5% to 15%, positively impacting economic and environmental aspects, particularly land occupation, soil salinization, and human health.
期刊介绍:
Developments in the Built Environment (DIBE) is a recently established peer-reviewed gold open access journal, ensuring that all accepted articles are permanently and freely accessible. Focused on civil engineering and the built environment, DIBE publishes original papers and short communications. Encompassing topics such as construction materials and building sustainability, the journal adopts a holistic approach with the aim of benefiting the community.