{"title":"Study on the Mechanism of Facet Formation Based on the Shape of Temperature Field","authors":"Hongyu Shao, Xixi Xiong, Xianglong Yang*, Desheng Wang, Laibin Zhao, Zhenxing Fu, Wenhao Han, Guojie Hu, Xiaomeng Li, Xuejian Xie, Guojian Yu, Xiufang Chen*, Xiaobo Hu and Xiangang Xu, ","doi":"10.1021/acs.cgd.4c0143810.1021/acs.cgd.4c01438","DOIUrl":null,"url":null,"abstract":"<p >This paper presents a systematic study of the facet formation on the wafer surface at the end of large-diameter 4H-SiC crystal growth, guided by numerical simulations. The influence of different temperature field shapes on facet position and shape was examined through resistivity tests and wafer scanning. Various models were developed to explain these effects, with facet shape changes ultimately interpreted through thermodynamic principles. Facets were found to form when the basal plane is tangent to the growth interface. The convexity <b><i>K</i></b> is directly proportional to the position <b><i>P</i></b> of the facet from the edge. The appearance of double facets on the same side due to large convexity <b><i>K</i></b><sub><b>1</b></sub>, confirms that the temperature field shape is a critical factor in determining the facet position. The facet shape can be viewed as a cross-section formed by the intersection of the basal plane and the growth interface. The length of the facet <b><i>H</i></b> is inversely related to the crystal convexity <b><i>K</i></b>. Both the width of the facet <b><i>D</i></b> and the inner angle <b>θ</b> are significantly influenced by the convexity <b><i>K</i></b><sub><b>1</b></sub>. As the convexity <b><i>K</i></b><sub><b>1</b></sub> increases, the inner angle <b>θ</b> decreases, while the width <b><i>D</i></b> increases.</p>","PeriodicalId":34,"journal":{"name":"Crystal Growth & Design","volume":"25 2","pages":"400–409 400–409"},"PeriodicalIF":3.2000,"publicationDate":"2025-01-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Crystal Growth & Design","FirstCategoryId":"92","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acs.cgd.4c01438","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
This paper presents a systematic study of the facet formation on the wafer surface at the end of large-diameter 4H-SiC crystal growth, guided by numerical simulations. The influence of different temperature field shapes on facet position and shape was examined through resistivity tests and wafer scanning. Various models were developed to explain these effects, with facet shape changes ultimately interpreted through thermodynamic principles. Facets were found to form when the basal plane is tangent to the growth interface. The convexity K is directly proportional to the position P of the facet from the edge. The appearance of double facets on the same side due to large convexity K1, confirms that the temperature field shape is a critical factor in determining the facet position. The facet shape can be viewed as a cross-section formed by the intersection of the basal plane and the growth interface. The length of the facet H is inversely related to the crystal convexity K. Both the width of the facet D and the inner angle θ are significantly influenced by the convexity K1. As the convexity K1 increases, the inner angle θ decreases, while the width D increases.
期刊介绍:
The aim of Crystal Growth & Design is to stimulate crossfertilization of knowledge among scientists and engineers working in the fields of crystal growth, crystal engineering, and the industrial application of crystalline materials.
Crystal Growth & Design publishes theoretical and experimental studies of the physical, chemical, and biological phenomena and processes related to the design, growth, and application of crystalline materials. Synergistic approaches originating from different disciplines and technologies and integrating the fields of crystal growth, crystal engineering, intermolecular interactions, and industrial application are encouraged.