{"title":"Isobaric Vapor–Liquid Equilibrium for the Binary System of Decamethyltetrasiloxane and Dodecamethylpentasiloxane at 11.0, 50.0, and 101.3 kPa","authors":"Zhen Chen, ZhanKun Jiang*, Jinyi Chen, Ping Lu, Chao Hua* and Qing Yuan*, ","doi":"10.1021/acs.jced.4c0049010.1021/acs.jced.4c00490","DOIUrl":null,"url":null,"abstract":"<p >The vapor–liquid equilibrium (VLE) data for decamethyltetrasiloxane (MD2M) and dodecamethylpentasiloxane (MD3M) are pivotal for efficient distillation separation process in the silicone industry. The isobaric VLE data for the binary system of MD2M + MD3M were determined at 11.0, 50.0, and 101.3 kPa using a modified Othmer still. The experimental data satisfied thermodynamic consistency tests, including Herington’s method and the Van Ness criterion. The VLE data were fitted using the NRTL, UNIQUAC, and Wilson activity coefficient models. The results show that the UNIQUAC model performs slightly better than the other models. The VLE data and model parameters reported here are essential for the design and simulation of separation processes for MD2M and MD3M, contributing valuable insights for industrial-scale operations.</p>","PeriodicalId":42,"journal":{"name":"Journal of Chemical & Engineering Data","volume":"70 1","pages":"408–415 408–415"},"PeriodicalIF":2.0000,"publicationDate":"2024-12-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Chemical & Engineering Data","FirstCategoryId":"1","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acs.jced.4c00490","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
The vapor–liquid equilibrium (VLE) data for decamethyltetrasiloxane (MD2M) and dodecamethylpentasiloxane (MD3M) are pivotal for efficient distillation separation process in the silicone industry. The isobaric VLE data for the binary system of MD2M + MD3M were determined at 11.0, 50.0, and 101.3 kPa using a modified Othmer still. The experimental data satisfied thermodynamic consistency tests, including Herington’s method and the Van Ness criterion. The VLE data were fitted using the NRTL, UNIQUAC, and Wilson activity coefficient models. The results show that the UNIQUAC model performs slightly better than the other models. The VLE data and model parameters reported here are essential for the design and simulation of separation processes for MD2M and MD3M, contributing valuable insights for industrial-scale operations.
期刊介绍：
The Journal of Chemical & Engineering Data is a monthly journal devoted to the publication of data obtained from both experiment and computation, which are viewed as complementary. It is the only American Chemical Society journal primarily concerned with articles containing data on the phase behavior and the physical, thermodynamic, and transport properties of well-defined materials, including complex mixtures of known compositions. While environmental and biological samples are of interest, their compositions must be known and reproducible. As a result, adsorption on natural product materials does not generally fit within the scope of Journal of Chemical & Engineering Data.
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