{"title":"Midinfrared Electroluminescence from CdSe Quantum Dots","authors":"Xingyu Shen, Philippe Guyot-Sionnest","doi":"10.1021/acsnano.4c18113","DOIUrl":null,"url":null,"abstract":"Midinfrared electroluminescence from the electron intraband transition is demonstrated with intrinsic CdSe colloidal quantum dots. The device consists of a thin film of CdSe dots and a layer of ZnO nanocrystals, sandwiched between two electrodes that enhance light outcoupling at 5 μm. At 100 mA and 15 V, the electron-to-photon efficiency is 0.40%, and the power conversion efficiency is 0.013%. The devices show good air and thermal stability. Electron transport layers and surface traps are discussed.","PeriodicalId":21,"journal":{"name":"ACS Nano","volume":"26 1","pages":""},"PeriodicalIF":15.8000,"publicationDate":"2025-02-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"ACS Nano","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1021/acsnano.4c18113","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Midinfrared electroluminescence from the electron intraband transition is demonstrated with intrinsic CdSe colloidal quantum dots. The device consists of a thin film of CdSe dots and a layer of ZnO nanocrystals, sandwiched between two electrodes that enhance light outcoupling at 5 μm. At 100 mA and 15 V, the electron-to-photon efficiency is 0.40%, and the power conversion efficiency is 0.013%. The devices show good air and thermal stability. Electron transport layers and surface traps are discussed.
期刊介绍:
ACS Nano, published monthly, serves as an international forum for comprehensive articles on nanoscience and nanotechnology research at the intersections of chemistry, biology, materials science, physics, and engineering. The journal fosters communication among scientists in these communities, facilitating collaboration, new research opportunities, and advancements through discoveries. ACS Nano covers synthesis, assembly, characterization, theory, and simulation of nanostructures, nanobiotechnology, nanofabrication, methods and tools for nanoscience and nanotechnology, and self- and directed-assembly. Alongside original research articles, it offers thorough reviews, perspectives on cutting-edge research, and discussions envisioning the future of nanoscience and nanotechnology.