Bimetallic covalent-organic frameworks (BMCOFs): Fundamentals and applications

Abstract

Bimetallic covalent-organic frameworks (BMCOFs) have emerged as a highly promising and versatile class of materials with exceptional catalytic properties and a wide range of applications. BMCOFs act as a bridge between metal-organic frameworks (MOFs) and covalent-organic frameworks (COFs), harnessing the unique properties and characteristics of both materials, resulting in maximum catalytic efficiency and the incorporation of advantageous features. The integration of two different metal species within the COF structure gives rise to a synergistic effect, leading to significantly enhanced catalytic performance when compared to monometallic counterparts.The synthesis of bimetallic COFs involves the meticulous incorporation of two different metal species into the COF, enabling precise control over composition and arrangement. This deliberate manipulation allows for the modulation of catalytic properties, fine-tuning the materials to suit specific applications. The interaction between the two metals and the COF backbone generates a synergistic effect where the combined properties of the metals and the COF structure surpass the capabilities of the individual components. This crucial synergistic effect plays a paramount role in unlocking the enhanced catalytic performance observed in BMCOFs.The unique electronic and geometric characteristics of the two metal species within bimetallic COFs facilitate cooperative interactions with the COF structure, enabling efficient charge transfer, electron delocalization, and improved catalytic activity. The presence of two metals in bimetallic COFs offers exciting opportunities for optimized electronic structures, adjustable redox potentials, and an increased number of active sites. These factors contribute to enhanced catalytic activity, selectivity, and stability, rendering BMCOFs highly desirable for various catalytic processes. Furthermore, the presence of multiple metals within the COF structure provides a rich and diverse landscape of catalytic sites, enabling efficient catalysis of complex chemical reactions.Overall, this paper explores the fundamental aspects of bimetallic COFs and highlights their significant potential in catalysis, showcasing their exceptional performance, unique characteristics, and diverse applications within the field.