Silver-Catalyzed Decarboxylative Coupling of Oxamic Acids with Styrenes to Synthesize E-Cinnamamides: A Distinguish Reaction Pathway.

IF 2.5 4区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

ChemistryOpen Pub Date : 2025-01-29 DOI:10.1002/open.202400513

Ru-Han A, Yong-Wang Huo, Xiao-Feng Wu

引用次数: 0

Abstract

A silver-catalyzed decarboxylative coupling of oxamic acids with styrenes has been developed to produce E-cinnamamides. Oxamic acids act as efficient precursors for carbamoy radicals. Based on the mechanistic experiments and intermediate analysis, the proposed mechanism involves radical addition to styrenes, followed by oxidation and solvent participation, ultimately leading to the formation of cinnamamides which is different from the reported cases.

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来源期刊

ChemistryOpen CHEMISTRY, MULTIDISCIPLINARY-

CiteScore

4.80

自引率

4.30%

发文量

143

审稿时长

1 months

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