Fluid Simulation and Dyeing Effect of a Multilayer Dye Dissolver for Supercritical Waterless Dyeing

IF 7.3 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Jun Lai, Lijun Dai, Ruchen Hong, Kai Ye, Tingting Huang, Lan Li, Tian Zhang, Wei Xiao, Jinxin Lin
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Abstract

Supercritical waterless dyeing is a kind of green dyeing technology, which has been expected by the dyeing industry. However, without dyeing auxiliaries, the formulation of high specific gravity dyes has been a difficult problem. Meanwhile, at high loadings, the agglomeration effect of dyes is enhanced, thereby influencing the dissolution efficiency and dyeing efficiency of the dyestuff. This study proposed a multilayer dye dissolver for dark and black dyeing in supercritical carbon dioxide. The structural soundness of the proposed design was verified by numerical simulation during the predesign process. Subsequently, dyeing results with different dye dissolvers demonstrated that the design of the multilayer dye dissolver could meet the requirements for dark and black dyeing. Furthermore, the samples exhibited satisfactory color fastness and K/S values. The color fastness of the samples was found to be at a level of 3–4 or above. Moreover, comprehensive energy consumption and carbon emission test results indicated that the equipment was capable of reducing energy consumption and carbon emissions by 92.56% and 92.05%, respectively, in comparison to conventional water dyeing. This provided an opportunity for further dissemination of supercritical waterless dyeing technology.

Abstract Image

超临界无水染色多层染料溶解剂的流体模拟及染色效果
超临界无水染色是一种绿色染色技术,一直受到印染行业的期待。然而,在没有染色助剂的情况下,高比重染料的配方一直是一个难题。同时,在高负荷下,染料的团聚效应增强,从而影响染料的溶解效率和染色效率。提出了一种用于超临界二氧化碳中深黑色染色的多层染料溶解剂。在预设计过程中,通过数值模拟验证了该设计的结构合理性。随后,不同染料溶解剂的染色结果表明,多层染料溶解剂的设计可以满足深色和黑色染色的要求。此外,样品具有令人满意的色牢度和K/S值。样品的色牢度为3-4或以上。综合能耗和碳排放测试结果表明,该设备与常规水染色相比,能耗和碳排放分别降低92.56%和92.05%。这为超临界无水染色技术的进一步推广提供了契机。
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来源期刊
ACS Sustainable Chemistry & Engineering
ACS Sustainable Chemistry & Engineering CHEMISTRY, MULTIDISCIPLINARY-ENGINEERING, CHEMICAL
CiteScore
13.80
自引率
4.80%
发文量
1470
审稿时长
1.7 months
期刊介绍: ACS Sustainable Chemistry & Engineering is a prestigious weekly peer-reviewed scientific journal published by the American Chemical Society. Dedicated to advancing the principles of green chemistry and green engineering, it covers a wide array of research topics including green chemistry, green engineering, biomass, alternative energy, and life cycle assessment. The journal welcomes submissions in various formats, including Letters, Articles, Features, and Perspectives (Reviews), that address the challenges of sustainability in the chemical enterprise and contribute to the advancement of sustainable practices. Join us in shaping the future of sustainable chemistry and engineering.
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