Jun Lai, Lijun Dai, Ruchen Hong, Kai Ye, Tingting Huang, Lan Li, Tian Zhang, Wei Xiao, Jinxin Lin
{"title":"Fluid Simulation and Dyeing Effect of a Multilayer Dye Dissolver for Supercritical Waterless Dyeing","authors":"Jun Lai, Lijun Dai, Ruchen Hong, Kai Ye, Tingting Huang, Lan Li, Tian Zhang, Wei Xiao, Jinxin Lin","doi":"10.1021/acssuschemeng.4c07661","DOIUrl":null,"url":null,"abstract":"Supercritical waterless dyeing is a kind of green dyeing technology, which has been expected by the dyeing industry. However, without dyeing auxiliaries, the formulation of high specific gravity dyes has been a difficult problem. Meanwhile, at high loadings, the agglomeration effect of dyes is enhanced, thereby influencing the dissolution efficiency and dyeing efficiency of the dyestuff. This study proposed a multilayer dye dissolver for dark and black dyeing in supercritical carbon dioxide. The structural soundness of the proposed design was verified by numerical simulation during the predesign process. Subsequently, dyeing results with different dye dissolvers demonstrated that the design of the multilayer dye dissolver could meet the requirements for dark and black dyeing. Furthermore, the samples exhibited satisfactory color fastness and <i>K</i>/<i>S</i> values. The color fastness of the samples was found to be at a level of 3–4 or above. Moreover, comprehensive energy consumption and carbon emission test results indicated that the equipment was capable of reducing energy consumption and carbon emissions by 92.56% and 92.05%, respectively, in comparison to conventional water dyeing. This provided an opportunity for further dissemination of supercritical waterless dyeing technology.","PeriodicalId":25,"journal":{"name":"ACS Sustainable Chemistry & Engineering","volume":"15 1","pages":""},"PeriodicalIF":7.3000,"publicationDate":"2025-01-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"ACS Sustainable Chemistry & Engineering","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1021/acssuschemeng.4c07661","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Supercritical waterless dyeing is a kind of green dyeing technology, which has been expected by the dyeing industry. However, without dyeing auxiliaries, the formulation of high specific gravity dyes has been a difficult problem. Meanwhile, at high loadings, the agglomeration effect of dyes is enhanced, thereby influencing the dissolution efficiency and dyeing efficiency of the dyestuff. This study proposed a multilayer dye dissolver for dark and black dyeing in supercritical carbon dioxide. The structural soundness of the proposed design was verified by numerical simulation during the predesign process. Subsequently, dyeing results with different dye dissolvers demonstrated that the design of the multilayer dye dissolver could meet the requirements for dark and black dyeing. Furthermore, the samples exhibited satisfactory color fastness and K/S values. The color fastness of the samples was found to be at a level of 3–4 or above. Moreover, comprehensive energy consumption and carbon emission test results indicated that the equipment was capable of reducing energy consumption and carbon emissions by 92.56% and 92.05%, respectively, in comparison to conventional water dyeing. This provided an opportunity for further dissemination of supercritical waterless dyeing technology.
期刊介绍:
ACS Sustainable Chemistry & Engineering is a prestigious weekly peer-reviewed scientific journal published by the American Chemical Society. Dedicated to advancing the principles of green chemistry and green engineering, it covers a wide array of research topics including green chemistry, green engineering, biomass, alternative energy, and life cycle assessment.
The journal welcomes submissions in various formats, including Letters, Articles, Features, and Perspectives (Reviews), that address the challenges of sustainability in the chemical enterprise and contribute to the advancement of sustainable practices. Join us in shaping the future of sustainable chemistry and engineering.