{"title":"Attosecond Rescattering of Laser-Assisted Electron-Proton Collision in Coulomb Potential.","authors":"Mohammad Noh Daud","doi":"10.1021/acs.jpca.4c07219","DOIUrl":null,"url":null,"abstract":"<p><p>This study investigates the motion of an electron in a Coulomb potential driven by an intense linearly polarized XUV laser pulse analyzed using Gordon-Volkov wave functions. The wave function is decomposed into spherical partial waves to model the scattered electron wave packet after the recollision with a proton. This interaction triggers high harmonic generation, producing coherent X-ray pulses with frequencies that are integer multiples of the XUV field. The research presents a novel method for achieving atomic-scale resolution at nanometer and subfemtosecond levels, enabling observation of electron-proton collisions on an attosecond time scale. It emphasizes the coupling of fields that create resonances in the scattered electron through photon energy exchange with XUV and X-ray pulses, leading to the formation of a Rydberg electron with energy levels up to <i>n</i> = 27 and angular momentum components <i>l</i> = 13 and <i>m</i> = ± 1. The combination of XUV and high-frequency X-ray fields introduces new nonperturbative nonlinear phenomena characterized by differential cross sections derived using the Floquet-Lippmann-Schwinger equation in the first-order Born approximation. The analysis shows that backward-forward scattering involves XUV-electron energy exchange, with peak intensity along the laser polarization vector, while sideways scattering, dominated by X-ray-electron interaction, peaks perpendicular to the polarization. Additionally, the laser-assisted scattering process results in temporary electron capture in a dressed proton-bound state, followed by escape and ejection, with the free electron ponderomotive energy exceeding 10<i>U</i><sub><i>p</i></sub>.</p>","PeriodicalId":59,"journal":{"name":"The Journal of Physical Chemistry A","volume":" ","pages":""},"PeriodicalIF":2.7000,"publicationDate":"2025-01-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"The Journal of Physical Chemistry A","FirstCategoryId":"1","ListUrlMain":"https://doi.org/10.1021/acs.jpca.4c07219","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
This study investigates the motion of an electron in a Coulomb potential driven by an intense linearly polarized XUV laser pulse analyzed using Gordon-Volkov wave functions. The wave function is decomposed into spherical partial waves to model the scattered electron wave packet after the recollision with a proton. This interaction triggers high harmonic generation, producing coherent X-ray pulses with frequencies that are integer multiples of the XUV field. The research presents a novel method for achieving atomic-scale resolution at nanometer and subfemtosecond levels, enabling observation of electron-proton collisions on an attosecond time scale. It emphasizes the coupling of fields that create resonances in the scattered electron through photon energy exchange with XUV and X-ray pulses, leading to the formation of a Rydberg electron with energy levels up to n = 27 and angular momentum components l = 13 and m = ± 1. The combination of XUV and high-frequency X-ray fields introduces new nonperturbative nonlinear phenomena characterized by differential cross sections derived using the Floquet-Lippmann-Schwinger equation in the first-order Born approximation. The analysis shows that backward-forward scattering involves XUV-electron energy exchange, with peak intensity along the laser polarization vector, while sideways scattering, dominated by X-ray-electron interaction, peaks perpendicular to the polarization. Additionally, the laser-assisted scattering process results in temporary electron capture in a dressed proton-bound state, followed by escape and ejection, with the free electron ponderomotive energy exceeding 10Up.
期刊介绍:
The Journal of Physical Chemistry A is devoted to reporting new and original experimental and theoretical basic research of interest to physical chemists, biophysical chemists, and chemical physicists.