Optimizing regeneration techniques and fixed-bed column application for leachate treatment utilizing carbon mineral composite

Abstract

The performance of carbon mineral-combined adsorbents in a batch and fixed column study was examined for removing chemical oxygen demand (COD) and ammoniacal nitrogen (NH₃-N), which typically found in landfill leachate. The batch experiment was carried out using various factors including adsorbent dosages and retention time, while column performance was evaluated by optimizing the influent flow rate. The surface of the composite adsorbent was examined using X-ray fluorescence (XRF), Fourier transform infrared (FTIR), and scanning electron microscopy (SEM) to determine any changes before and after column operations. The XRF analysis of the composite adsorbent reveals a high concentration of calcium oxide and silica oxide as the primary compounds. The main functional groups in the composite adsorbent included O–H, N–H, O–C, C–N, C–O, and Si–O–Si. The SEM analysis revealed that the composite adsorbent contains heterogeneous pores and a rough surface. The reduction rates achieved were 86% for COD, with an optimum adsorption capacity of 31.3 mgg⁻¹, and 80% for NH₃-N, with an optimum adsorption capacity of 29.8 mgg⁻¹. The breakthrough capacities for COD and NH₃-N adsorption were 6.55 and 4.24 mgg⁻¹, respectively. However, optimal empty-bed contact times (EBCTs) in minutes were 480. The performance efficiency of the column for COD and NH₃-N was 0.9978% and 0.9913%, by utilizing fresh composite adsorbent, and these number figures increased to (≥ 0.9998%) respectively after the regeneration process. The Adams–Bohart constant for COD from 5.30 × 10^–6 to 4.92 × 10^–6 mL/min-mg and NH₃-N from 2.90 × 10^–5 to 4.52 × 10^–5 mL/min-mg respectively was found to increase with increasing flow rates from 1.5 to 3.0 mLmin⁻¹. Therefore, COD and NH₃-N adsorption on composite adsorbent at flow rates of 1.5 mLmin⁻¹ was considered appropriate from the context of this study. In summary, this research has successfully shown that the use of composites as an adsorbent is a viable and suitable for the removal of COD and NH₃-N from leachate, indicating their potential for use in real-world industrial wastewater treatment could further enhance their practical applications.