{"title":"Realizing p-type InSb with enhanced thermoelectric performance via Cd doping","authors":"Qing Wang, Zhiliang Li, Zhipeng Li, Xinqi Liu, Yuli Xue, Jianglong Wang, Shufang Wang","doi":"10.1063/5.0249667","DOIUrl":null,"url":null,"abstract":"InSb is a promising mid-temperature thermoelectric material, and its n-type thermoelectric properties have been widely studied. For thermoelectric device applications, it is necessary to have p-type counterparts. Here, we report the realization of p-type InSb with enhanced thermoelectric performance via Cd doping. A high-power factor of 1.91 × 10−3 W m−1 K−2 is obtained in p-type In0.93Cd0.07Sb at 723 K due to the increased carrier concentration. Moreover, the lattice thermal conductivity is decreased to 2.0 W m−1 K−1 owing to the significant multiscale phonon scattering and the suppressed bipolar diffusion effect. Ultimately, the peak zT value of 0.40 is achieved at 723 K in p-type In0.93Cd0.07Sb, which surpasses most contemporary p-type InSb materials. This study demonstrates a simple strategy for fabricating p-type InSb with high performance and holds promise in advancing the development of InSb-based TE devices.","PeriodicalId":8094,"journal":{"name":"Applied Physics Letters","volume":"15 1","pages":""},"PeriodicalIF":3.5000,"publicationDate":"2025-01-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Applied Physics Letters","FirstCategoryId":"101","ListUrlMain":"https://doi.org/10.1063/5.0249667","RegionNum":2,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"PHYSICS, APPLIED","Score":null,"Total":0}
引用次数: 0
Abstract
InSb is a promising mid-temperature thermoelectric material, and its n-type thermoelectric properties have been widely studied. For thermoelectric device applications, it is necessary to have p-type counterparts. Here, we report the realization of p-type InSb with enhanced thermoelectric performance via Cd doping. A high-power factor of 1.91 × 10−3 W m−1 K−2 is obtained in p-type In0.93Cd0.07Sb at 723 K due to the increased carrier concentration. Moreover, the lattice thermal conductivity is decreased to 2.0 W m−1 K−1 owing to the significant multiscale phonon scattering and the suppressed bipolar diffusion effect. Ultimately, the peak zT value of 0.40 is achieved at 723 K in p-type In0.93Cd0.07Sb, which surpasses most contemporary p-type InSb materials. This study demonstrates a simple strategy for fabricating p-type InSb with high performance and holds promise in advancing the development of InSb-based TE devices.
期刊介绍:
Applied Physics Letters (APL) features concise, up-to-date reports on significant new findings in applied physics. Emphasizing rapid dissemination of key data and new physical insights, APL offers prompt publication of new experimental and theoretical papers reporting applications of physics phenomena to all branches of science, engineering, and modern technology.
In addition to regular articles, the journal also publishes invited Fast Track, Perspectives, and in-depth Editorials which report on cutting-edge areas in applied physics.
APL Perspectives are forward-looking invited letters which highlight recent developments or discoveries. Emphasis is placed on very recent developments, potentially disruptive technologies, open questions and possible solutions. They also include a mini-roadmap detailing where the community should direct efforts in order for the phenomena to be viable for application and the challenges associated with meeting that performance threshold. Perspectives are characterized by personal viewpoints and opinions of recognized experts in the field.
Fast Track articles are invited original research articles that report results that are particularly novel and important or provide a significant advancement in an emerging field. Because of the urgency and scientific importance of the work, the peer review process is accelerated. If, during the review process, it becomes apparent that the paper does not meet the Fast Track criterion, it is returned to a normal track.