{"title":"A highly visible-transparent thermochromic smart window with broadband infrared modulation for all-season energy savings.","authors":"Yi Jiang, Yunlong Wang, Deshuo Kong, Zipeng Chen, Zhengwei Yang, Ningning Cao, Haowen Chi, Shining Zhu, Qiuhong Zhang, Jia Zhu, Bin Zhu","doi":"10.1093/nsr/nwae408","DOIUrl":null,"url":null,"abstract":"<p><p>Thermochromic smart windows effectively reduce the energy consumption for buildings through passive light modulation including the transmission of visible (T<sub>Vis</sub>) and near-infrared (T<sub>NIR</sub>) light, and the emissivity of mid-infrared (ε<sub>MIR</sub>) light in response to ambient temperature change. However, thermochromic windows that maintain high T<sub>Vis</sub> while modulating T<sub>NIR</sub> and ε<sub>MIR</sub> simultaneously are highly desirable but still challenging. Here, we develop a thermochromic smart window based on a two-way shape memory polymer to enable reversible transformation and achieve T<sub>NIR</sub> modulation of 44.0% and ε<sub>MIR</sub> modulation of 76.5% while maintaining high T<sub>Vis</sub> (>50%). Compared to traditional windows based on silica glass, this device shows 4°C lower temperature in summer daytime, 2°C higher in winter daytime, and 1°C higher in spring nighttime. It is expected that our device can achieve greater annual energy savings in comparison with commercial glass anywhere in the world and promote the progress of thermochromic windows for energy-efficient buildings.</p>","PeriodicalId":18842,"journal":{"name":"National Science Review","volume":"12 2","pages":"nwae408"},"PeriodicalIF":16.3000,"publicationDate":"2024-11-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11737393/pdf/","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"National Science Review","FirstCategoryId":"103","ListUrlMain":"https://doi.org/10.1093/nsr/nwae408","RegionNum":1,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2025/2/1 0:00:00","PubModel":"eCollection","JCR":"Q1","JCRName":"MULTIDISCIPLINARY SCIENCES","Score":null,"Total":0}
引用次数: 0
Abstract
Thermochromic smart windows effectively reduce the energy consumption for buildings through passive light modulation including the transmission of visible (TVis) and near-infrared (TNIR) light, and the emissivity of mid-infrared (εMIR) light in response to ambient temperature change. However, thermochromic windows that maintain high TVis while modulating TNIR and εMIR simultaneously are highly desirable but still challenging. Here, we develop a thermochromic smart window based on a two-way shape memory polymer to enable reversible transformation and achieve TNIR modulation of 44.0% and εMIR modulation of 76.5% while maintaining high TVis (>50%). Compared to traditional windows based on silica glass, this device shows 4°C lower temperature in summer daytime, 2°C higher in winter daytime, and 1°C higher in spring nighttime. It is expected that our device can achieve greater annual energy savings in comparison with commercial glass anywhere in the world and promote the progress of thermochromic windows for energy-efficient buildings.
期刊介绍:
National Science Review (NSR; ISSN abbreviation: Natl. Sci. Rev.) is an English-language peer-reviewed multidisciplinary open-access scientific journal published by Oxford University Press under the auspices of the Chinese Academy of Sciences.According to Journal Citation Reports, its 2021 impact factor was 23.178.
National Science Review publishes both review articles and perspectives as well as original research in the form of brief communications and research articles.