Effective removal of As5+ from aqueous medium using date palm fiber biochar/chitosan/glutamine nanocomposite: kinetic and thermodynamic studies

Abstract

In the current work, three adsorbent materials were developed: biochar derived from date palm fiber (C), date palm fiber biochar/chitosan nanoparticles (CCS), and biochar/chitosan nanoparticle composite supplemented with glutamine (CCSG). These compounds were used as solid adsorbents to remove As⁵⁺ from polluted water. Several characterization approaches were used to investigate all the synthesized solid adsorbents, including thermogravimetric analysis, N₂ adsorption/desorption isotherm, scanning electron microscopy, transmission electron microscopy (TEM), attenuated total reflectance with Fourier transform infrared, and zeta potential. Date palm fiber biochar/chitosan/glutamine nanocomposite (CCSG) demonstrated good thermal stability, with a maximum specific surface area of 518.69 m²/g, a mesoporous size of 2.06 nm, total pore volume of 0.25 cm³/g, TEM average particle size of 38 nm, and pH_PZC of 6.9. Contact time (5–60 min), pH (1–9), starting As⁵⁺ concentration (50–500 mg/L), adsorbent dose (0.1–2.0 g/L), temperature (27–45 °C), and ionic strength (0.05–0.40 mol/L) were among the sorption parameters that were investigated in order to improve the adsorption conditions. It is observed that the modified samples were effectively able to remove As⁵⁺ (CCS; 256.0 and CCSG; 376.0 mg/g) than unmodified ones (C; 150.5 mg/g). The As⁵⁺ removal procedure corresponded well with Langmuir isotherm model. Thermodynamic and kinetic experiments show that the Elovich, pseudo-first order, and Van’t Hoff plot with endothermic, spontaneous, and physisorption nature are the best fitted models. EDTA has the highest desorption efficiency percentage (98.8%). CCSG demonstrated enhanced reusability after six application cycles of As⁵⁺ adsorption/desorption, with only a 4% decrease in the efficiency of adsorption. This work shows that adding glutamine to the DPF biochar/chitosan composite reinforces it, resulting in the fabrication of a solid adsorbent that shows promise for use in water remediation.