Surfactant-based interface capture towards the development of 2D-printed photonic structures.

Abstract

This study focuses on fabricating photonic crystals (PCs) by surfactant-based particle capture at the gas-liquid interface of evaporating sessile droplets. The captured particles form interfacial films, resulting in ordered monolayer depositions manifesting iridescent structural colors. The particle dynamics behind the ordered arrangement is delineated. This arrangement is influenced by the alteration in particles' hydrophobicity, charge, and internal flow introduced by the surfactant addition. The influence of surfactant and particle concentrations on the phenomenon is also investigated. The work demonstrates a drop-by-drop technique to scale up the formation of PCs. Furthermore, the work is extended towards demonstrating the utilization of this mechanism to fabricate arbitrary PCs efficiently by direct writing technique. The particle coverage in directly written patterns is influenced by printing speed and particle concentration, which are adjusted to achieve covert photonic patterns. Finally, the replication of colloidal PC onto a flexible polymer with minimal colloid transfer is demonstrated using soft lithography.