Understanding the Ag–S interface stability and electrocatalytic activity of CO2 electroreduction in atomically precise Ag25 nanoclusters†

IF 4.2 2区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY
Yuting Ye , Xia Zhou , Yuping Chen , Likai Wang , Qing Tang
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引用次数: 0

Abstract

Elucidating the catalytic properties of metal nanoclusters (NCs) with essentially the same structure but different core metals is of fundamental interest. Our current studies have demonstrated that the thiolated Ag25(SR)18 NC exhibits SR ligand leaching dynamics and electrocatalytic activity in CO2 reduction distinct from those of its Au25(SR)18 NC structural analogue.

Abstract Image

原子精密Ag25纳米团簇中Ag-S界面稳定性和CO2电还原活性的研究
阐明具有基本相同结构但核心金属不同的金属纳米团簇(NCs)的催化性能具有重要意义。我们目前的研究表明,硫代Ag25(SR)18 NC具有SR配体浸出动力学和二氧化碳还原电催化活性,与Au25(SR)18 NC结构类似物不同。
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来源期刊
Chemical Communications
Chemical Communications 化学-化学综合
CiteScore
8.60
自引率
4.10%
发文量
2705
审稿时长
1.4 months
期刊介绍: ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.
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