Palladium-catalyzed amination oxidation of electron-rich olefins in green media†

IF 9.3 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Green Chemistry Pub Date : 2025-01-08 DOI:10.1039/D4GC05771F

Yongpeng Zheng, Yaodan Wu, Jianxiao Li, Wanqing Wu, Shaorong Yang, Chaorong Qi and Huanfeng Jiang

引用次数: 0

Abstract

A palladium-catalyzed amination oxidation of electron-rich olefins with anilines under air at room temperature in ionic liquids was accomplished. Herein, H₂O₂ serves as the oxidant and the oxygen source of the carbonyl group. Notably, this new approach provides a practical and straightforward route to access a broad range of privileged amino acid structures with good yields and excellent regioselectivities. Significantly, internal olefins were also compatible with this transformation.

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来源期刊

Green Chemistry 化学-化学综合

CiteScore

16.10

自引率

7.10%

发文量

677

审稿时长

1.4 months

期刊介绍： Green Chemistry is a journal that provides a unique forum for the publication of innovative research on the development of alternative green and sustainable technologies. The scope of Green Chemistry is based on the definition proposed by Anastas and Warner (Green Chemistry: Theory and Practice, P T Anastas and J C Warner, Oxford University Press, Oxford, 1998), which defines green chemistry as the utilisation of a set of principles that reduces or eliminates the use or generation of hazardous substances in the design, manufacture and application of chemical products. Green Chemistry aims to reduce the environmental impact of the chemical enterprise by developing a technology base that is inherently non-toxic to living things and the environment. The journal welcomes submissions on all aspects of research relating to this endeavor and publishes original and significant cutting-edge research that is likely to be of wide general appeal. For a work to be published, it must present a significant advance in green chemistry, including a comparison with existing methods and a demonstration of advantages over those methods.