George Curtis, Doraiswami Ramkrishna, Vivek Narsimhan
{"title":"Brownian bridges for contained random walks","authors":"George Curtis, Doraiswami Ramkrishna, Vivek Narsimhan","doi":"10.1002/aic.18658","DOIUrl":null,"url":null,"abstract":"Using linear operator techniques, we demonstrate an efficient method for investigating rare events in stochastic processes. Specifically, we examine contained trajectories, which are continuous random walks that only leave a specified region of phase space after a set period of time <span data-altimg=\"/cms/asset/a0469ccf-17af-4b97-93c8-3c46f35fdc73/aic18658-math-0001.png\"></span><mjx-container ctxtmenu_counter=\"250\" ctxtmenu_oldtabindex=\"1\" jax=\"CHTML\" role=\"application\" sre-explorer- style=\"font-size: 103%; position: relative;\" tabindex=\"0\"><mjx-math aria-hidden=\"true\" location=\"graphic/aic18658-math-0001.png\"><mjx-semantics><mjx-mrow><mjx-mi data-semantic-annotation=\"clearspeak:simple\" data-semantic-font=\"italic\" data-semantic- data-semantic-role=\"latinletter\" data-semantic-speech=\"upper T\" data-semantic-type=\"identifier\"><mjx-c></mjx-c></mjx-mi></mjx-mrow></mjx-semantics></mjx-math><mjx-assistive-mml display=\"inline\" unselectable=\"on\"><math altimg=\"urn:x-wiley:00011541:media:aic18658:aic18658-math-0001\" display=\"inline\" location=\"graphic/aic18658-math-0001.png\" overflow=\"scroll\" xmlns=\"http://www.w3.org/1998/Math/MathML\"><semantics><mrow><mi data-semantic-=\"\" data-semantic-annotation=\"clearspeak:simple\" data-semantic-font=\"italic\" data-semantic-role=\"latinletter\" data-semantic-speech=\"upper T\" data-semantic-type=\"identifier\">T</mi></mrow>$$ T $$</annotation></semantics></math></mjx-assistive-mml></mjx-container>. We show that such trajectories can be efficiently generated through the use of a Brownian Bridge, derived via the solution to the Backward Fokker–Planck (BFP) equation. Using linear operator techniques, we place the BFP operator in self-adjoint form and show that in the asymptotic limit <span data-altimg=\"/cms/asset/128708a3-6ffd-4c86-b14d-78bdfa6190b3/aic18658-math-0002.png\"></span><mjx-container ctxtmenu_counter=\"251\" ctxtmenu_oldtabindex=\"1\" jax=\"CHTML\" role=\"application\" sre-explorer- style=\"font-size: 103%; position: relative;\" tabindex=\"0\"><mjx-math aria-hidden=\"true\" location=\"graphic/aic18658-math-0002.png\"><mjx-semantics><mjx-mrow data-semantic-children=\"0,2\" data-semantic-content=\"1\" data-semantic- data-semantic-role=\"inequality\" data-semantic-speech=\"upper T much greater than 1\" data-semantic-type=\"relseq\"><mjx-mi data-semantic-annotation=\"clearspeak:simple\" data-semantic-font=\"italic\" data-semantic- data-semantic-parent=\"3\" data-semantic-role=\"latinletter\" data-semantic-type=\"identifier\"><mjx-c></mjx-c></mjx-mi><mjx-mo data-semantic- data-semantic-operator=\"relseq,≫\" data-semantic-parent=\"3\" data-semantic-role=\"inequality\" data-semantic-type=\"relation\" rspace=\"5\" space=\"5\"><mjx-c></mjx-c></mjx-mo><mjx-mn data-semantic-annotation=\"clearspeak:simple\" data-semantic-font=\"normal\" data-semantic- data-semantic-parent=\"3\" data-semantic-role=\"integer\" data-semantic-type=\"number\"><mjx-c></mjx-c></mjx-mn></mjx-mrow></mjx-semantics></mjx-math><mjx-assistive-mml display=\"inline\" unselectable=\"on\"><math altimg=\"urn:x-wiley:00011541:media:aic18658:aic18658-math-0002\" display=\"inline\" location=\"graphic/aic18658-math-0002.png\" overflow=\"scroll\" xmlns=\"http://www.w3.org/1998/Math/MathML\"><semantics><mrow data-semantic-=\"\" data-semantic-children=\"0,2\" data-semantic-content=\"1\" data-semantic-role=\"inequality\" data-semantic-speech=\"upper T much greater than 1\" data-semantic-type=\"relseq\"><mi data-semantic-=\"\" data-semantic-annotation=\"clearspeak:simple\" data-semantic-font=\"italic\" data-semantic-parent=\"3\" data-semantic-role=\"latinletter\" data-semantic-type=\"identifier\">T</mi><mo data-semantic-=\"\" data-semantic-operator=\"relseq,≫\" data-semantic-parent=\"3\" data-semantic-role=\"inequality\" data-semantic-type=\"relation\">≫</mo><mn data-semantic-=\"\" data-semantic-annotation=\"clearspeak:simple\" data-semantic-font=\"normal\" data-semantic-parent=\"3\" data-semantic-role=\"integer\" data-semantic-type=\"number\">1</mn></mrow>$$ T\\gg 1 $$</annotation></semantics></math></mjx-assistive-mml></mjx-container>, the set of paths contained in a specified region is equivalent to paths on a modified potential energy landscape that is related to the dominant eigenfunction of the self-adjoint BFP operator. We demonstrate this idea on several example problems, one of which is the Graetz problem, where one is interested in the survival time of a particle diffusing in tube flow.","PeriodicalId":120,"journal":{"name":"AIChE Journal","volume":"5 1","pages":""},"PeriodicalIF":3.5000,"publicationDate":"2025-01-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"AIChE Journal","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.1002/aic.18658","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
引用次数: 0
Abstract
Using linear operator techniques, we demonstrate an efficient method for investigating rare events in stochastic processes. Specifically, we examine contained trajectories, which are continuous random walks that only leave a specified region of phase space after a set period of time . We show that such trajectories can be efficiently generated through the use of a Brownian Bridge, derived via the solution to the Backward Fokker–Planck (BFP) equation. Using linear operator techniques, we place the BFP operator in self-adjoint form and show that in the asymptotic limit , the set of paths contained in a specified region is equivalent to paths on a modified potential energy landscape that is related to the dominant eigenfunction of the self-adjoint BFP operator. We demonstrate this idea on several example problems, one of which is the Graetz problem, where one is interested in the survival time of a particle diffusing in tube flow.
期刊介绍:
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