Polyanion-type iron-based sulfate cathode materials: from fundamental research to industrialization

IF 18.9 1区材料科学 Q1 CHEMISTRY, PHYSICAL

Energy Storage Materials Pub Date : 2025-01-20 DOI:10.1016/j.ensm.2025.104049

Xiaoyan Shi, Yun Wan, Zhiming Zhou, Wenxi Kuang, Xiaomin Chen, Jian Chen, Xunzhu Zhou, Junxiang Liu, Shulei Chou, Lin Li

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Abstract

Sodium-ion batteries (SIBs) with the merits of abundant sodium resources and low cost are considered significant supplements to lithium-ion batteries in large-scale energy storage systems. Among the discovered cathode materials for SIBs, iron-based sulfate materials have attracted widespread attention due to their high operating voltage, superior structural stability, and high safety. In this review, we summarize the research achievements of iron-based sulfate cathode materials in fundamental research, as well as provide a comprehensive overview of its industrialization progress for the first time. Meanwhile, effective modification strategies (including morphology design, hybridization with carbon materials, and construction of heterostructure) and further research directions to boost the sodium storage performance of iron-based sulfate cathode materials are also proposed. This review can provide valuable guidance for developing high-performance iron-based sulfate cathode materials for practical application.

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多阴离子型铁基硫酸盐阴极材料：从基础研究到产业化

钠离子电池具有钠资源丰富、成本低等优点，被认为是大规模储能系统中锂离子电池的重要补充。在已发现的sib正极材料中，铁基硫酸盐材料因其工作电压高、结构稳定性好、安全性高等优点而受到广泛关注。本文综述了铁基硫酸盐正极材料在基础研究方面的研究成果，并首次对其产业化进展进行了全面概述。同时，提出了提高铁基硫酸盐正极材料储钠性能的有效改性策略（包括形貌设计、与碳材料杂化、异质结构构建等）和进一步的研究方向。本文综述可为开发高性能的铁基硫酸盐正极材料提供有价值的指导。

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来源期刊

Energy Storage Materials Materials Science-General Materials Science

CiteScore

33.00

自引率

5.90%

发文量

652

审稿时长

27 days

期刊介绍： Energy Storage Materials is a global interdisciplinary journal dedicated to sharing scientific and technological advancements in materials and devices for advanced energy storage and related energy conversion, such as in metal-O2 batteries. The journal features comprehensive research articles, including full papers and short communications, as well as authoritative feature articles and reviews by leading experts in the field. Energy Storage Materials covers a wide range of topics, including the synthesis, fabrication, structure, properties, performance, and technological applications of energy storage materials. Additionally, the journal explores strategies, policies, and developments in the field of energy storage materials and devices for sustainable energy. Published papers are selected based on their scientific and technological significance, their ability to provide valuable new knowledge, and their relevance to the international research community.