Progress and challenges of transition metal-based catalysts regulation for Li-CO2 batteries

IF 18.9 1区材料科学 Q1 CHEMISTRY, PHYSICAL

Energy Storage Materials Pub Date : 2025-01-20 DOI:10.1016/j.ensm.2025.104047

Shasha Xiao, Ying Xiao, Shilin Hu, Tonghui Zhang, Gang He, Jihui Jing, Shimou Chen

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引用次数: 0

Abstract

Lithium-carbon dioxide (Li−CO₂) batteries have gained wide attention in recent years due to their high energy density and effective CO₂ fixation and conversion. However, the sluggish CO₂ transformation kinetics always result in high polarization voltage and poor cycling stability, seriously impeding their development. Electrochemical catalysts especially transition metal (TM)-based ones with modulated micro- and electronic-structure have attracted significant interest and exhibited great promising in promoting the CO₂ reduction and evolution reactions owing to their unique d orbital. In this review, we summarize the hot modifying strategies and the related mechanism of TM-based catalysts including Ru, Ir, Pt and non-nobel transition metals such as Mo, Co, Cu, Mn, Fe, Ni, Cr, Cd, V, In, W and Re etc. applied in Li−CO₂ batteries. The latest research progress along with some remaining issues is discussed in detail. Finally, the perspectives and challenges of TMs-based catalysts for Li−CO₂ battery are presented, aiming to provide valuable guidance for the design and optimization of advanced cathodic catalysts in high-efficiency Li−CO₂ batteries.

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锂-CO2 电池过渡金属催化剂调控的进展与挑战

近年来，锂-二氧化碳（Li - CO2）电池因其高能量密度和有效的二氧化碳固定和转化而受到广泛关注。然而，CO2转化动力学缓慢，往往导致极化电压高，循环稳定性差，严重阻碍了其发展。基于过渡金属（TM）的微结构和电子结构调制型电化学催化剂由于其独特的d轨道，在促进CO2还原和演化反应方面具有很大的应用前景。本文综述了Ru、Ir、Pt等tm基催化剂和Mo、Co、Cu、Mn、Fe、Ni、Cr、Cd、V、In、W、Re等非诺贝尔过渡金属在Li−CO2电池中的热改性策略及其机理。对最新的研究进展及存在的问题进行了详细的讨论。最后，提出了tms型锂- CO2电池阴极催化剂的发展前景和面临的挑战，旨在为高效锂- CO2电池阴极催化剂的设计和优化提供有价值的指导。

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来源期刊

Energy Storage Materials Materials Science-General Materials Science

CiteScore

33.00

自引率

5.90%

发文量

652

审稿时长

27 days

期刊介绍： Energy Storage Materials is a global interdisciplinary journal dedicated to sharing scientific and technological advancements in materials and devices for advanced energy storage and related energy conversion, such as in metal-O2 batteries. The journal features comprehensive research articles, including full papers and short communications, as well as authoritative feature articles and reviews by leading experts in the field. Energy Storage Materials covers a wide range of topics, including the synthesis, fabrication, structure, properties, performance, and technological applications of energy storage materials. Additionally, the journal explores strategies, policies, and developments in the field of energy storage materials and devices for sustainable energy. Published papers are selected based on their scientific and technological significance, their ability to provide valuable new knowledge, and their relevance to the international research community.