DNDMH Enabled C(sp3)−H Nitration of Aryl Alkenes

IF 4.3 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemical Communications Pub Date : 2025-01-18 DOI:10.1039/d4cc06671e

Zhiyuan Wang, Yali Li, Xuena Ding, Yuancheng Sun, Chongchong Chen, Wei Sun, Xiangdong Hu

引用次数: 0

Abstract

C(sp3)−H bond nitration opens facile access to nitro compounds unreachable from traditional nitration pathway. The work describes herein a C(sp3)−H bond nitration of aryl alkenes with the application of DNDMH, a nitration reagent developed previously in our lab. Notably, this novel nitration process presents good regioselectivity and chemoselectivity between C(sp3)−H nitration and C(sp2)−H nitration.

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DNDMH使C(sp3)−H硝化芳基烯烃

C(sp3)−H键硝化可以方便地获得传统硝化途径无法获得的硝基化合物。本文描述了一种C(sp3)−H键的芳基烯烃硝化与DNDMH的应用，一种硝化试剂，以前在我们的实验室开发。值得注意的是，这种新的硝化过程在C(sp3)−H硝化和C(sp2)−H硝化之间表现出良好的区域选择性和化学选择性。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Chemical Communications 化学-化学综合

CiteScore

8.60

自引率

4.10%

发文量

2705

审稿时长

1.4 months

期刊介绍： ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.