The Impact of Electric Fields on Processes at Electrode Interfaces

IF 51.4 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Chemical Reviews Pub Date : 2025-01-16 DOI:10.1021/acs.chemrev.4c00487

Zhuoran Long, Jinhui Meng, Lydia R. Weddle, Pablo E. Videla, Jan Paul Menzel, Delmar G. A. Cabral, Jinchan Liu, Tianyin Qiu, Joseph M. Palasz, Dhritiman Bhattacharyya, Clifford P. Kubiak, Victor S. Batista, Tianquan Lian

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Abstract

The application of external electric fields to influence chemical reactions at electrode interfaces has attracted considerable interest in recent years. However, the design of electric fields to achieve highly efficient and selective catalytic systems, akin to the optimized fields found at enzyme active sites, remains a significant challenge. Consequently, there has been substantial effort in probing and understanding the interfacial electric fields at electrode/electrolyte interfaces and their effect on adsorbates. In this review, we examine recent advances in experimental, computational, and theoretical studies of the interfacial electric field, the origin of the vibrational Stark effect of adsorbates on electrode surfaces, and the effects of electric fields on reactions at electrode/electrolyte interfaces. We also discuss recent advances in control of charge transfer and chemical reactions using magnetic fields. Finally, we outline perspectives on key areas for future studies.

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电场对电极界面过程的影响

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本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Chemical Reviews 化学-化学综合

CiteScore

106.00

自引率

1.10%

发文量

278

审稿时长

4.3 months

期刊介绍： Chemical Reviews is a highly regarded and highest-ranked journal covering the general topic of chemistry. Its mission is to provide comprehensive, authoritative, critical, and readable reviews of important recent research in organic, inorganic, physical, analytical, theoretical, and biological chemistry. Since 1985, Chemical Reviews has also published periodic thematic issues that focus on a single theme or direction of emerging research.