Microstructure and properties of polycrystalline diamond with AlCoCrFeNi2.1 eutectic high-entropy alloys as binder

IF 23.2 2区 材料科学 Q1 MATERIALS SCIENCE, COMPOSITES
Wei Liu, Yue Li, Deli Gao, Yezeng He, Yasser Vasseghian, Akbar Hojjati-Najafabadi
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Abstract

The performance of polycrystalline diamond (PCD) tools largely depends on the adhesion and catalyzing effect of the binder phase. In this study, AlCoCrFeNi2.1 eutectic high-entropy alloy (HEA) was used as a new binder material to synthesize the PCD samples. First-principles calculations showed that the interface strength between HEA and diamond is better than that between cobalt and diamond, suggesting that the HEA/PCD combination has the potential to exhibit better properties than the conventional cobalt/PCD tools. PCD samples with HEA as the binder phase were successfully synthesized using high-pressure and high-temperature conditions of 8.0 GPa and 1500–1700℃. Several key performance indicators, including thermal expansion coefficient, Vickers hardness, transverse rupture strength, compressive strength, and wear resistance were measured to comprehensively evaluate the overall performance of the well-sintered HEA/PCD. The results showed that, compared with conventional cobalt/PCD, the HEA/PCD exhibited a lower thermal expansion coefficient and reduced graphitization of diamond at high temperatures above 920 K. HEA/PCD also demonstrated better mechanical properties than Co/PCD, including higher hardness, and greater transverse rupture strength and compressive strength. Moreover, over the same cutting distance against the granite block, HEA/PCD tools exhibited significantly lower wear loss than Co/PCD, indicating superior wear resistance. This study provides new insights and strategies for the design and optimization of PCD binders and PCD tools.

以AlCoCrFeNi2.1共晶高熵合金为粘结剂的聚晶金刚石的组织与性能
聚晶金刚石(PCD)刀具的性能在很大程度上取决于粘结相的粘附和催化作用。本研究采用AlCoCrFeNi2.1共晶高熵合金(HEA)作为新型粘结材料合成PCD样品。第一性原理计算表明,HEA与金刚石之间的界面强度优于钴与金刚石之间的界面强度,这表明HEA/PCD组合具有比传统钴/PCD工具更好的性能。在8.0 GPa、1500 ~ 1700℃的高压高温条件下,成功合成了以HEA为粘结相的PCD样品。通过测量热膨胀系数、维氏硬度、横向断裂强度、抗压强度和耐磨性等关键性能指标,综合评价烧结良好的HEA/PCD的整体性能。结果表明,与传统的钴/PCD相比,HEA/PCD在920 K以上的高温下具有较低的热膨胀系数和较低的金刚石石墨化程度。HEA/PCD也表现出比Co/PCD更好的力学性能,包括更高的硬度、更高的横向断裂强度和抗压强度。此外,在与花岗岩块相同的切割距离上,HEA/PCD工具的磨损损失明显低于Co/PCD工具,这表明HEA/PCD工具具有更高的耐磨性。该研究为PCD粘结剂和PCD工具的设计和优化提供了新的见解和策略。
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来源期刊
CiteScore
26.00
自引率
21.40%
发文量
185
期刊介绍: Advanced Composites and Hybrid Materials is a leading international journal that promotes interdisciplinary collaboration among materials scientists, engineers, chemists, biologists, and physicists working on composites, including nanocomposites. Our aim is to facilitate rapid scientific communication in this field. The journal publishes high-quality research on various aspects of composite materials, including materials design, surface and interface science/engineering, manufacturing, structure control, property design, device fabrication, and other applications. We also welcome simulation and modeling studies that are relevant to composites. Additionally, papers focusing on the relationship between fillers and the matrix are of particular interest. Our scope includes polymer, metal, and ceramic matrices, with a special emphasis on reviews and meta-analyses related to materials selection. We cover a wide range of topics, including transport properties, strategies for controlling interfaces and composition distribution, bottom-up assembly of nanocomposites, highly porous and high-density composites, electronic structure design, materials synergisms, and thermoelectric materials. Advanced Composites and Hybrid Materials follows a rigorous single-blind peer-review process to ensure the quality and integrity of the published work.
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