High efficiency of solution-processed inverted organic solar cells enabled by an aluminum oxide conjunction structure†

IF 32.4 1区 材料科学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Yi Yang, Mengqi Cui, Zhengyan Jiang, Ruijia Zhang, Xinjun He, Hui Liu, Biao Zhou and Wallace C. H. Choy
{"title":"High efficiency of solution-processed inverted organic solar cells enabled by an aluminum oxide conjunction structure†","authors":"Yi Yang, Mengqi Cui, Zhengyan Jiang, Ruijia Zhang, Xinjun He, Hui Liu, Biao Zhou and Wallace C. H. Choy","doi":"10.1039/D4EE05337K","DOIUrl":null,"url":null,"abstract":"<p >The lack of solution-processed hole transport layers (HTLs) has become an obstacle not only to developing all-solution-processed inverted organic solar cells (OSCs) but also to enabling their full potential for high-throughput fabrication. One of the major problems is the distinct difference in surface-free energy between most HTLs and the organic bulk heterojunction (BHJ) active layer, which causes inherent wetting behavior problems and poor film quality. Here, we unveil the interesting features of the aluminum oxide (Al<small><sub>2</sub></small>O<small><sub>3</sub></small>) nanocrystal-based conjunction structure in improving the interfacial properties between a solution-processed HTL (namely PIDT-F:POM) and the organic active layer. Our results showed that the structure of Al<small><sub>2</sub></small>O<small><sub>3</sub></small>/HTL can generally be applied to different active layers in inverted OSCs, providing high power conversion efficiency (PCE) and stability. By additional solution-processing of the Al<small><sub>2</sub></small>O<small><sub>3</sub></small> conjunction structure on the hydrophobic active layer, the wettability of the hydrophilic HTL on the modified BHJ surface is significantly improved, as evidenced by the reduced water contact angles. Remarkably, the new structure of BHJ/Al<small><sub>2</sub></small>O<small><sub>3</sub></small>/PIDT-F:POM offers superior electrical properties, explained by the excellent hole extraction capability and reduced interfacial recombination. Consequently, Al<small><sub>2</sub></small>O<small><sub>3</sub></small>/PIDT-F:POM yields high PCEs, reaching 18.4% in inverted OSCs. Notably, their PCE and stability are even better than those of the control cells made from widely adopted evaporated molybdenum trioxide (MoO<small><sub>3</sub></small>). The work demonstrates the new concept of establishing efficient solution-processed HTLs and alternative pathways for promoting inverted OSCs for practical applications.</p>","PeriodicalId":72,"journal":{"name":"Energy & Environmental Science","volume":" 4","pages":" 1963-1971"},"PeriodicalIF":32.4000,"publicationDate":"2025-01-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Energy & Environmental Science","FirstCategoryId":"88","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2025/ee/d4ee05337k","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0

Abstract

The lack of solution-processed hole transport layers (HTLs) has become an obstacle not only to developing all-solution-processed inverted organic solar cells (OSCs) but also to enabling their full potential for high-throughput fabrication. One of the major problems is the distinct difference in surface-free energy between most HTLs and the organic bulk heterojunction (BHJ) active layer, which causes inherent wetting behavior problems and poor film quality. Here, we unveil the interesting features of the aluminum oxide (Al2O3) nanocrystal-based conjunction structure in improving the interfacial properties between a solution-processed HTL (namely PIDT-F:POM) and the organic active layer. Our results showed that the structure of Al2O3/HTL can generally be applied to different active layers in inverted OSCs, providing high power conversion efficiency (PCE) and stability. By additional solution-processing of the Al2O3 conjunction structure on the hydrophobic active layer, the wettability of the hydrophilic HTL on the modified BHJ surface is significantly improved, as evidenced by the reduced water contact angles. Remarkably, the new structure of BHJ/Al2O3/PIDT-F:POM offers superior electrical properties, explained by the excellent hole extraction capability and reduced interfacial recombination. Consequently, Al2O3/PIDT-F:POM yields high PCEs, reaching 18.4% in inverted OSCs. Notably, their PCE and stability are even better than those of the control cells made from widely adopted evaporated molybdenum trioxide (MoO3). The work demonstrates the new concept of establishing efficient solution-processed HTLs and alternative pathways for promoting inverted OSCs for practical applications.

Abstract Image

由氧化铝连接结构实现的溶液处理倒置有机太阳能电池的高效率
溶液处理的空穴传输层(HTLs)的缺乏不仅阻碍了全溶液处理的倒置有机太阳能电池(OSCs)的发展,而且阻碍了其高通量制造的潜力。其中一个主要问题是大多数HTLs与有机体异质结(BHJ)活性层之间的表面自由能存在明显差异,导致其固有的润湿行为和较差的膜质量。在这里,我们揭示了氧化铝(Al2O3)纳米晶体连接结构在改善溶液处理的html(即PIDT-F:POM)与有机活性层之间的界面性能方面的有趣特征。结果表明,Al2O3/HTL结构可广泛应用于倒装OSCs的不同有源层,具有较高的功率转换效率和稳定性。通过对疏水活性层上Al2O3连接结构进行额外的溶液处理,可以显著提高亲水性HTL在改性BHJ表面的润湿性,表现为水接触角的减小。值得注意的是,BHJ/Al2O3/PIDT-F:POM的新结构具有优异的电学性能,从而赋予了反向OSCs,这可以解释为优异的孔洞提取能力和减少的界面复合。因此,Al2O3/PIDT-F:POM在倒转OSCs中产生高pce,达到18.4%。值得注意的是,它们的PCE和稳定性甚至优于由广泛采用的蒸发三氧化钼(MoO3)制成的对照电池。这项工作展示了建立高效的解决方案处理html的新概念,以及促进倒立osc在实际应用中的替代途径。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 求助全文
来源期刊
Energy & Environmental Science
Energy & Environmental Science 化学-工程:化工
CiteScore
50.50
自引率
2.20%
发文量
349
审稿时长
2.2 months
期刊介绍: Energy & Environmental Science, a peer-reviewed scientific journal, publishes original research and review articles covering interdisciplinary topics in the (bio)chemical and (bio)physical sciences, as well as chemical engineering disciplines. Published monthly by the Royal Society of Chemistry (RSC), a not-for-profit publisher, Energy & Environmental Science is recognized as a leading journal. It boasts an impressive impact factor of 8.500 as of 2009, ranking 8th among 140 journals in the category "Chemistry, Multidisciplinary," second among 71 journals in "Energy & Fuels," second among 128 journals in "Engineering, Chemical," and first among 181 scientific journals in "Environmental Sciences." Energy & Environmental Science publishes various types of articles, including Research Papers (original scientific work), Review Articles, Perspectives, and Minireviews (feature review-type articles of broad interest), Communications (original scientific work of an urgent nature), Opinions (personal, often speculative viewpoints or hypotheses on current topics), and Analysis Articles (in-depth examination of energy-related issues).
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信